CV, Research & Publications
CURRICULUM VITAE
Gambarotta Sandro, full professor, tenured.
Member of School of Graduate Studies and Research:
MSc, University of Pisa (Italy) 1975
PhD, University of Pisa (Italy) 1979
EMPLOYMENT HYSTORY:
1995- Professor, University of Ottawa
1989-1995 Associate Professor, University of Ottawa
1986-1989 Associate Professor, University of Groningen, The Netherlands
1985-1986 Senior Research Associate, Columbia University, New York, USA
1983-1984 Assistant Professor (Ricercatore Confermato), University of Pisa, Italy
1981-1983 Research Associate, University of Pisa, Italy
1980 Postdoctoral fellow, University of Ottawa
d) HONOURS:
CIC Alcan Award 1996
FCIC
G. Schloss Lecturer, University of Chicago Dec 2002
2012 Faculty of Science researcher of the Year
e) SCHOLARLY AND PROFESSIONAL ACTIVITIES:
Director X-Ray Core Facility (ended 2018)
NSERC GS Committee 24 2001-2003
NSERC RTI-GC 2015-2016
FRQ –GC 2016
Occupational H&S Committee 2013-2016
1999-2002 Member of the Editorial Board of Organometallics
Director OCCI 2002-2005
1992-1998 Member of the Editorial Board of Journal of Organometallic Chemistry
f) GRADUATE SUPERVISION
Career Number: 20 M.A., 14 Ph.D.
Completed: 17 M.A., 12 Ph.D.
In progress:
g) GRADUATE AND UNDERGRADUATE COURSES:
Transition Metal Chemistry, Catalysis. Organometallic chemistry (every second year)
CHM 1311 (General Chemistry), CHM 1321 (Organic Chemistry), CHM 4311 (Selected Topics inorganic chemistry). CHM 4380 (basic of X-ray crystallography), CHM 8302A-B (general organometallic chemistry)
h) RESEARCH FUNDING:
2015-2018 335,412 USD$ (per year) SABIC Collaborative research on water splitting
2013-2015 40,000(per year) NSERC Accelerator Award
2013-2018 84,000(per year) NSERC Discovery (per year)
2011-2012 148,800 NSERC RTI
2011-2013 98,000 (per year) Dutch Polymer Institute (per year)
2010-2012 50,000 CFI-IOF (support to the X-ray Core facility)
2010-2012 25,000 University of Ottawa (Support to the Core facility)
2010 670,000 CFI -LOF (X-Ray diffractometer)
2008-2011 30,000 LyondellBasell (per year)
2007-2011 92,000 NSERC (research individual) (per year)
2009-2011 98,000 Dutch Polymer Institute (per year)
2007-2009 106,000 Dutch Polymer Institute (per year)
2004-2007 120,000 NSERC (strategic per year)
Research Interest
Our research activity is directed towards both catalysis and low-valent metals for molecular activation. In catalysis our interest started with a study in vanadium chemistry by using a ligand system which has received substantial attention in the literature for its role in sustaining exceptional catalytic activity with late metals. Besides finding another potent catalyst, our paper in vanadium chemistry was the first insight into the direct involvement of the ligand system in the organometallic chemistry of the metal center (J. Am. Chem. Soc. 1999, 121, 9318). In an attempt to generalize these unique findings we have also tested middle metals and found what seemingly is an endless variety of transformations (J. Am. Chem. Soc. 2002,124,12268). Last but not least we also find that the ability of this ligand to work as electron storage allows a curious ambiguity in the metal oxidation state, which positively affects both catalytic performances and molecular activation (J. Am. Chem. Soc. 2005, 127, 13019). It is just in the last few months that we have made what we are convinced to be a major breakthrough. By designing a new type of hemilabile catalytic system, we are in the fortunate position of being able of preparing families of single component catalysts of extremely high polymerization activity (Angew. Chem. Int. Ed.2007, 46, 6119). Still focusing on processes forming C-C bond from ethylene, we have started a project aimed at understanding the selective oligomerization. In search for working hypothesis, our research has initially focused on studying established catalytic systems and has yielded important insights into the factors promoting activity and selectivity (J. Am. Chem. Soc. 2006, 128, 9238, Angew. Chem. Int. Ed. Engl. 2006, 45, 7050, Angew. Chem. Int. Ed. Engl. 2008in press).
In a separate line of research we pursue our interest for understanding activation of dinitrogen. Our recent work in f-block elements chemistry has provided evidences for the cooperative interaction of one-electron reductants on the same dinitrogen substrate, a feature somehow related to the behavior of the Fe cofactor of nitrogenase. Instead, by using a multi-electron reductant such a uranium and transient low-valent thorium synthons we have obtained the sole existing examples of dinitrogen cleavage and partial hydrogenation promoted by a f-block element (Angew. Chem. Int. Ed. Engl. 2002, 41, 3433, Angew. Chem. Int. Ed. Engl. 2003,42, 4958, cited by C&En, Angew. Chem. Int. Ed. Engl 2003, 42, 814. Cited by C&En).
Very recently we have turned our attention to CO2 activation an water splitting (see list of most recent publication below). To this end, we have discovered unprecedented bonding mode of CO2 to a metal center (Angewandte Chemie Int Ed Engl. VIP accepted) and linked such a coordination to the enhancement of radical behavior of CO2 (Chem. Eur.J. 2017, 23,17269–17278.), extracting H atom from the solvent in an overall facile reduction process (Angew. Chem. Int. Ed. 2018, 57, 10928). We also have designed a new system where shuttle chemistry is used to perform a two stage water splitting (Dalton 2017,46, 49).
Most Recent Publications
262. Camilo J. Viasus, Nicholas P. Alderman, Sebastiano Licciulli, Ilia Korobkov and Sandro Gambarotta.
Radical behavior of CO2 versus its deoxygenation promoted by vanadium aryloxide complexes: how the geometry of intermediate CO2-adducts determines the reactivity.
Chem. Eur.J. 2017, 23,17269–17278.
263. Jacob M. Sommers, Nicholas P. Alderman, Camilo J. Viasus, Sandro Gambarotta
Revisiting the behavior of BiVO4as a carbon dioxide reduction photo-catalyst.
Dalton Transaction 2017, 6404
264. Nicholas P. Alderman1, Jacob M. Sommers1, Camilo J. Viasus, Christine H.T. Wang, Virginie Peneau, SandroGambarotta, Balamurugan Vidjayacoumar, Khalid A. Bahily-Al:
Photochemical Water Splitting Mediated by a C1 Shuttle
Dalton 2017,46, 49.
265. Camilo J. Viasus, Nicholas P. Alderman, Bulat Gabidullin and Sandro Gambarotta.
Reaction of CO2with a Vanadium(II) Aryloxide: Synergistic Activation of CO2/-oxo Groups towards H-Atom Radical Extraction.
Angew. Chem. Int. Ed.2018, 57, 10928-10932.
266. Nicholas P. Alderman, Virginie Peneau,Camilo J. Viasus, Ilia Korobkov, Balamurugan Vidjayacoumar, Khalid Albahily and Sandro Gambarotta,
Syn-gas from Waste: the Reduction of CO2with H2S.
React. Chem. Eng., 2019, 4, 763-771.
267. Camilo J. Viasus, Nicholas P. Alderman, Virginie Peneau, Bulat Gabidullin, Balamurugan Vidjayacoumar, Khalid Albahily and Sandro Gambarotta.
Two-Step Catalytic Dehydrogenation of Formic Acid to CO2via Formaldehyde.
International Journal of Hydrogen Energy. 2019,44, 3, 1534-1543
268. Nicholas P Alderman, Virginie Peneau, Camilo J. Viasus, Ilia Korobkov, Balamurugan Vidjacoumar, Khalid Bahily-Al and Sandro Gambarotta.
Efficient Reduction of Formic Acid to Formaldehyde by Zinc.
Canadian Journal of Chemistry., 2019, 97(1), 42-45.
269. Camilo J. Viasus, Sandro Gambarotta, Bulat Gabidullin.
"Linear and Bridging End-On coordination modes of CO2 on vanadium(II) and (III) aryloxides"
Angewandte Chemie Int Ed Engl. VIP accepted
Complete List of Publications
1. S. GambarottaThesis, Pisa, 1975.
2. E. Ciuffarin, S. Gambarotta, M. Isola, and L. Senatore
"Chemistry of sulphenates in acidic media".
J. Chem. Soc., Perkin II,1978, 554.
3. E. Ciuffarin, S. Gambarotta, M. Isola, L. Senatore, and M. Cioni
"Racemization of non-cleavable sulphoxides in non-aqueous solvents"
J. Chem. Res., (S),1978, 270-271. (M), 1978, 3429.
4. E. Ciuffarin, S. Gambarotta, M. Isola, and L. Senatore
"Oxygen exchange between sulphoxides and sulphides in non-aqueous solvents"
J. Chem. Res.,(S), 1978, 272-723. (M), 1978, 3442.
5. E. Ciuffarin and S. Gambarotta
"Racemization of cleavable sulphoxides and chlorynolysis of cleavable sulphides in non-aqueous and aqueous solvents".
J. Chem. Res., (S),1978, 274 (M), 1978, 3454.
6. S. Gambarotta, M. Isola, L. Senatore, and E. Ciuffarin
“NMR detection of complexes of sulfones with chloride and bromide ions"
Gazz. Chim. Ital., 1982, 112, 297.
7. S. Gambarottaand H. Alper,
"Phase transfer catalysis using cobalt tricarbonyl nitrosyl".
J. Organomet. Chem., 1981, 212, C23-C26.
8. S. Gambarotta and H. Alper
"The carbonylation of phase transfer agents".
J. Organomet. Chem., 1980, 194, C19-C21.
9. S. Gambarotta, K. Hachem, and H. Alper
"The mild Rhodium(I) and phase transfer catalyzed, dehydrogenation of benzylic alcohols".
Can. J. Chem., 1980, 194, 1599.
10. S. Gambarottaand H. Alper
"Phase transfer catalyzed hydroacylation of allenes".
J. Org. Chem., 1981, 45, 2142
11. M. Pasquali, S.Gambarotta, C. Floriani, A. Chiesi-Villa, and C. Guastini
"Activation of CO2-like molecules: synthetic and structural studies on a h2-C,N bonded carbodiimide and its conversion into a h2-C,N metal bonded amidinyl ligand".
Inorg. Chem., 1981, 20, 165.
12. S. Gambarotta, M. Pasquali, C. Floriani, A. Chiesi-Villa, and C. Guastini
"Carbon dioxide equivalents activation: h1-O and h2-C,O metal anchored carbonylic functional groups to a bis(cyclopentadienyl)vanadium unit".
Inorg. Chem., 1981, 20, 1173.
13. S. Gambarotta, F. Arena, C. Floriani, and A. Gaetani-Manfredotti
"Activation of CO2-like molecules by a multifunctional complex: possible pathways leading to C-C bond formation from one carbon functional group".
J. Chem. Soc., Chem. Commun., 1982, 835.
14. S. Gambarotta, F. Arena, C. Floriani, and P.F. Zanazzi
"Carbon dioxide fixation: bifunctional complexes containinig acidic and basic sites working as reversible carriers".
J. Am. Chem. Soc.,1982, 104, 5083.
15. S. Gambarotta, C. Floriani, A. Chiesi-Villa, and C. Guastini
"Titanium-promoted syntheses of carbohydrazido ligand from carbon monoxide and a diazoalkane: diazoalkane coordination and activation by titanocene and vanadocene".
J. Am. Chem. Soc.,1982, 104, 1918.
16. S. Gambarotta, C. Floriani, A. Chiesi-Villa, and C. Guastini
"Metal-formaldehyde chemistry: coordination, disproportionation, and Lewis-acid-promoted transformation to oxymethylene derivatives".
J. Am. Chem. Soc.,1982, 104, 2019.
17. S. Gambarotta, C. Floriani, M. Basso-Bert and C. Guastini
"Nitrogen-carbon and nitrogen-hydrogen bond formation by insertion of a diazoalkane into a metal-carbon and metal-hydrogen bonds".
J. Chem. Soc. Chem. Comm., 1982, 324.
18. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"Carbon-carbon bond formation and cleavage resulting from a long range metal-promoted redox process".
J. Chem. Soc. Chem. Comm., 1982, 756.
19. S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini and M.L. Fiallo
"Alkali cations controlling the reactivity of Co(II) schiff base complexes synthesis of a µ-persulphido ligand from S8reacting with a Co(II) oxygen carrier compound".
J. Chem. Soc. Chem. Comm., 1982, 503
20. S. Gambarotta,C. Floriani, A. Chiesi-Villa and C. Guastini
"Nitrogen-nitrogen bond cleavage and reduction in diphenyldiazomethane and azobenzene by a Ti(III) complex".
J. Chem. Soc. Chem. Comm., 1982, 1015.
21. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"Monocyclopentadienyldichlorotitanium(III) as a free radical-like reagent for reducing N-N multiple bonds in azoand diazo- compounds".
J. Am. Chem. Soc., 1983, 105, 7295.
22. S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini and F. Urso
"Carbon-carbon bond forming and breaking by a metal-assisted redox process in a nickel(II) Schiff base complex".
Inorg. Chem., 1983, 22, 3966.
23. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"Decamethylvanadocene chemistry: synthesis, structure and reactions with carbon monoxide and isocyanides".
Inorg. Chem., 1984, 23, 1739.
24. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"Genesis, bonding mode and reaction with CO of an oxymethylene unit".
J. Am. Chem. Soc.,1983, 105, 1690.
25. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"Hydrazonido ligands forming from the insertion of diazoalkanes into zirconium-carbon and zirconium-hydrogen bonds".
Inorg. Chem., 1983, 22, 2029.
26. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"Decamethylvanadocene forming a disulphur complex from elemental sulphur and desulphurization reactions".
J. Chem. Soc. Chem. Comm., 1983, 184.
27. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"Ring contraction in an arylcopper(I) promoted by a sulphur donor ligand pentamesitylcopper(I) forms a tetramesitylcopper(I)".
J. Chem. Soc. Chem. Comm., 1983, 1156.
28. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"A termally stable and soluble arylsilver (I): synthesis and structure of mesitylsilver (I)".
J. Chem. Soc. Chem. Comm., 1983, 1087.
29. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"A homoleptic arylmanganese (II): synthesis and structure of a thermally stable trinuclear mesitylmanganese (II)".
J. Chem. Soc. Chem. Comm., 1983, 1128.
30. S. Gambarotta, S. Strologo, C. Floriani, A. Chiesi-Villa and C. Guastini
"Synthesis and structure of a mononuclear Copper(I) complex containing the copper(I)-phenyl functionality".
Organometallics1984, 3, 1444.
31. S. Gambarotta, M.L. Fiallo, C. Floriani, A. Chiesi-Villa and C. Guastini
"Reactivity of decamethylvanadocene with phenyl isothiocyanates and carbonyl sulphide: reactions related to the desulfurization of the thiocarbonyl group".
Inorg. Chem., 1984, 23, 3532,.
32. S. Gambarotta, S. Strologo, C. Floriani, A. Chiesi-Villa and C. Guastini
"Insertion of CO2-like molecules into zirconium-carbon bonds: reactivity of dialkylbis(cyclopentadienyl)zirconium(IV) with carbon dioxide, diphenylketene, arylisocyanates, p-tolylcarbodiimide".
Inorg. Chem., 1985, 24, 654,.
33. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"A homoleptic arylgold(I): synthesis and structure of the pentanuclear mesitylgold(I)".
J. Chem. Soc. Chem. Comm., 1983, 1304
34. S. Gambarotta, M. Mazzanti, C. Floriani and M. Zehnder
"A tetranuclear polyfunctional sodium-vanadium(III) complex containing a vanadium(III)vanadium(III) double bond".
J. Chem. Soc. Chem. Comm., 1984, 1116.
35. S. Gambarotta, F. Corazza, C. Floriani and M. Zehnder
"A tetranuclear iron(II)-sodium complex formed from the complexation of sodium ethoxide by N,N-ethylenebis(acetylacetoneiminato)iron(II)".
J. Chem. Soc. Chem. Comm., 1984, 1305,.
36. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini
"Ethylene rearrangement to hydrido-ethylidine ligands and formaldehyde decarboxylation in the synthesis of (h5-C5H5)4Co4derivatives".
J. Organomet. Chem., 1985, 296, C6,.
37. S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Gusastini
"A tris -aryl vanadium(III) derivative: structural determination of trimesitylvanadium(III)-tetrahydrofuran".
J. Chem. Soc. Chem. Comm., 1984, 886.
38. S. Gambarotta, A Chiesi-Villa and C. Guastini
"Synthesis, X-ray structure and reactions of phenylimidodecamethyl vanadocene".
J. Organomet. Chem., 1984, 270, C49.
39. S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini
"Carbon dioxide and formaldehyde coordination on Molybdenocene: metal and hydrogen bonds of the C1 molecule in the solid state structure".
J. Am. Chem. Soc., 1985, 107, 2985.
40. S. Gambarotta, M. Mazzanti, C. Floriani, A. Chiesi-Villa, C. Guastini
"Organometallic derivatives of N,N-ethylenebis(acetylacetoneiminato)vanadium (III) containing vanadium-carbon bond".
J. Chem. Soc. Chem. Comm., 1985, 829.
41. S. Gambarotta, S. Strologo, C. Floriani, A. Chiesi-Villa, C. Guastini
"Stepwise reduction of carbon dioxide to formaldehyde and methanol: reactions of CO2and CO2-like molecules with hydridochlorobis(cyclopentadienyl)zirconium (IV)".
J. Am. Chem. Soc., 1985, 107, 6278.
42. S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini
"Metal-formaldehyde chemistry: metal promoted elementary transformations of formaldehyde".
Organometallics, 1986, 5, 2425
43. S. Gambarotta, M. Mazzanti, C. Floriani, A. Chiesi-Villa
"Vanadium(III)-schiff base complexes: a synthetic and structural study".
Inorg. Chem. 1986, 25, 2308.
44. S. Gambarotta, S. Stella, C. Floriani, A. Chiesi-Villa, C. Guastini
"Synthesis and structure of the Co Ti complex {µ3-[(C5H5)2TiOCl]}2{(C5H5)3Co3}: CO reduction by two different metal centers".
Angew. Chem. Int. Ed. Engl.1986, 25, 254.
45. S. Ciurli, S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini
"Cobalt-meso-tetraphenylporphyrine complexes: synthesis and structure of [Na(thf)3]2[Co(TPP)]".
Angew. Chem. Int. Ed. Engl. 1986, 25, 553.
46. S. Gambarotta, S. Stella, C. Floriani, A. Chiesi-Villa, C. Guastini
"Co-oligomerization of diphenylketene and ethylene promoted by (h5-cyclopentadienyl)bis(ethylene)cobalt(I): synthesis and X-ray structure of a heterocycle containing cobaly(III)."
J. Chem. Soc. Dalton Trans. 1987, 1789.
47. S. Gambarotta, M. Bracci, C. Floriani, A. Chiesi-Villa, C. Guastini
"Tetranuclear amido complexes of copper(I): a synthetic and structural study".
J. Chem. Soc. Dalton Trans. 1987, 1883.
48. C. Floriani, S. Gambarotta, A. Chiesi-Villa, C. Guastini
"Reaction of elemental sulphur with bis(pentamethylcyclopentadienyl) vanadium derivatives: disulphido and µ-sulphido complexes. Crystal structures of [V(h-C5Me5)2(S2)] and [V2(h-C5Me5)2Cl2(µ-S)2].
J. Chem. Soc. Dalton Trans. 1987, 2099.
49. E.M. Meyer, S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini
"Polynuclear aryl derivatives of group 11 metals: synthesis, solid state-solution structural relationship and reactivity with phosphines".
Organometallics1989, 8, 1067.
(Independent Research)
50. S. Gambarotta, M.Y.N. Chiang
"The synthesis and X-rays structure of CpZr(II)Cl(dmpe)2(dmpe= dimethyl phosphinoethane) via reduction reaction of CpZrCl3".
J. Chem. Soc. Chem. Comm. 1987, 698.
51. S. Gambarotta, M.Y.N. Chiang
"The synthesis of a diamagnetic fulvalene zirconium (III) derivative. The crystal structure of [h5:h5-C10H8)(h5-C5H5)2Zr2(µ-Cl)2]."
Organometallics,1987, 6, 897.
52. S. Gambarotta, A. Chiesi-Villa, C. Guastini
"Synthesis, reactivity and crystal structure of CpV(CO)3tht. A mild condition synthetic pathway to substitution derivatives of CpV(CO)4. The preparation and X-ray characterization of cis-CpV(CO)2(a,a‘-dipyridyl)".
Inorg. Chem., 1988, 27, 99.
53. S. Gambarotta, F. van Bolhuis, M. Chiang
"Monomeric versus dimeric vanadium(III) aryloxide formation. The syntheses and X-ray structures of [(O-2,6-ArMe2)2(µ-O-2,6-ArMe2)V(III)]2thf and [(O-2,6-ArMe2)3V(III)(pyridine)2]".
Inorg. Chem. 1987, 26, 4301.
54. Y. Wielstra, S. Gambarotta, M. Chiang, H. Roedelof
"Monocyclopentadienyl zirconium and hafnium (II) chemistry: Synthesis and reactivity of CpM(CO)2(dmpe)Cl [M=Zr,Hf; Cp=cyclopentadienyl; dmpe=1,2-bis(dimethylphosphino)ethane] via mild condition carbonylation reaction of CpM(dmpe)2Cl. The crystal structure of CpZr(CO)2(dmpe)Cl".
Organometallics1988, 7, 2177
55. M.Y. Chiang, S. Gambarotta, F. van Bolhuis
"Dinuclear and diamagnetic zirconium (III) derivatives without Zr-Zr bond. Synthesis and X-ray structure of {Cp2Zr[µ-P(CH3)2]}2and (Cp2Zr)2[µ-P(CH3)2]".
Organometallics 1988,7, 1864.
56. Y. Wielstra, S. Gambarotta, M.Y. Chiang
"[1,2-bis(dimethylphosphino)ethane] (cyclopentadienyl)(methyl) zirconium(II) [CpZrMe(dmpe)2]: a catalyst precursor for the selective dimerization of ethylene to 1-butene".
Organometallics1988, 7, 1866.
57. Y. Wielstra, S. Gambarotta, M.Y. Chiang
"The elusive Zr(III). (invited review)
Rec. Trav. Chim. Pays Bas, 1989, 108, 1.
58. Y. Wielstra, A. Meetsma, S. Gambarotta
"Synthesis of new monomeric zirconium and hafnium hydrido-butadiene complexes. The X-ray structure of CpZrH(dmpe)(h4-butadiene)".
Organometallics1989, 8, 258.
59. Y. Wielstra, S. Gambarotta, A. Meetsma, J. deBoer
"Preparation and X-ray structure of [Cp2Zr(µ-I)]2. A thermally unstable Zr(III) complex".
Organometallics1989, 8, 250.
60. J. Edema, S. Gambarotta, F. van Bolhuis, W.J.J. Smeets, A.L. Spek
"New classes of monomeric and dimeric Cr(II) aryloxides: syntheses and structures.
Inorg. Chem. 1989, 28, 1407.
61. J. Edema, S. Gambarotta, F. van Bolhuis, A.L. Spek
"Chromium (II) alkoxides: synthesis and crystal structure of the monomeric [(RO)4Cr][Na(tmeda)]2[R=2,6-dimethylphenyl] and dimeric [(RO)8Cr2][NaL]4[R=phenyl; L=thf,Py] without Cr-Cr bond. An insight into the question of Cr-Cr quadruple bond formation?".
J. Am. Chem. Soc. 1989, 111, 2142.
62. J. Edema, S. Gambarotta, A.L. Spek
"Synthesis and X-ray structure of the first homoleptic and dinuclear Cr(II) amide {[(i-Pr)2N]Cr[µ-(i-Pr)2N]}2".
Inorg. Chem. 1989, 28, 812.
63. Y. Wielstra, S. Gambarotta, A. Meetsma, J. deBoer, M. Chiang
"Alkynes regioselective dimerization, co-cyclotrimerization and catalytic cyclotrimerization promoted by monocyclopentadienyl Zr(II) complexes. The preparation and X-ray structure of Cp(dmpe)XZr[(R)C=C(R’)C(R)=C=(R’)] [R=CH3, t-Bu; R’=H, CH3; dmpe=1,2-bis(dimethylphosphino)ethane]".
Organometallics1989, 8, 2696.
64. Y. Wielstra, S. Gambarotta, A. Spek
"The controversy about the thermal stability of biscyclopentadienyl Zr(III) halides Cp2ZrX [Cp = C5H5, CH3C5H4]. Synthesis and X-ray structure of [Cp2ZrI]2via photolysis or themolysis of Cp2Zr(i-Bu)X".
Organometallics1989, 8, 2948.
65. J. Edema, S. Gambarotta, A. Spek, W. Smeets
"Preparation and X-ray structure of tetramethyldibenzotetraaza [14]annulene chromium dimer. The first multiply bonded Cr(II) dimer without bridging ligands".
Inorg. Chem. 1989, 28, 3782.
66. J. Edema, S. Gambarotta, A. Meetsma
"Divalent vanadium and dinitrogen fixation: the preparation and X-ray structure of (µ-N2){[o-Me2NCH2)C6H4]2V(py)}2(THF)2".
J. Am. Chem. Soc. 1989, 111, 6878.
67. Y. Wielstra, S. Gambarotta, A.L. Spek
"Monocyclopentadienyl Zr and Hf alkyls: synthesis hydrogen-transfer reactions and catalytic features in the reactivity with a-olefins. The X-ray structure of CpZr(h4-butadiene)(dmpe)Cl".
Organometallics1990, 9, 572.
68. J. Edema, W. Stauthamer, S. Gambarotta, F. van Bolhuis, W. Smeets, A. Spek
"Novel V(II) amine complexes: a facile entry in the chemistry of divalent vanadium synthesis and characterization of mononuclear L4VCl2 [L = amine, pyridine]. The X-ray structure of trans-(TMEDA)2VCl2and trans-Mz2VPy2[Mz = o-C6H4CH2N(CH3)2".
Inorg. Chem. 1990, 29, 1302.
69. J. Edema, S. Gambarotta, A. Meetsma, F. van Bolhuis, A. Spek
"The unpredictable structural features of chromium(II) pyrrolyls: synthesis and X-ray structures of monomeric square-planar (h1-2,5-Me2C4H2N)CrPy2, square-pyramidal (h1-C4H4N)2Cr(py)3and polymeric [(h1-2,5-Me2C4H2N)4CrNa(THF)2(Et2O)]n. An aborted Cr-Cr quadruple bond formation?"
Inorg. Chem. 1990, 29, 2147
70. J. Edema, S. Gambarotta, F. van Bolhuis, W. Smeets, A. Spek, M. Chiang
"Monomeric Cr(II) aryl complexes: the crystal structure of cis-Mes2Cr(THF)2(THF), [cis-Mes2Cr(bipy)](THF), [Mes4CrLi2(THF)2](THF) and Ph4CrLi2(THF)4".
J. Organomet. Chem. 1990, 389, 47
71. Y. Wielstra, S. Gambarotta, A.L. Spek, W.J.J. Smeets
"Binuclear Zr(III) and Zr(IV) complexes: the mild oxidation of low-valent zirconium as a synthetic pathway to a class of triand tetravalent zirconium fulvalene complexes. The molecular structures of [h5:h5-C10H8][CpZrSPh]2, [h5:h5-C10H8][CpZr(CH3)2]2, [h5:h5-C10H8][CpZr]2[µ-S]2
Organometallics1990, 9, 2142
72. Y. Wielstra, S. Gambarotta, A. Meetsma, S. Khan
Cyclopentadiene functionalization versus fulvalene formation in the oxidation of [(h1:h5-C5H4)ZrCp(PMe3)]2: the preparation and the crystal structures of [(h1:h5-C5H4)ZrCp]2[µ-NSiMe3] and [(h1:h5-C5H4)[ZrCpSPh][µ-NSiMe3][CpZr (C5H4SPh)].
Organometallics1990, 9, 876
73. J.J.H. Edema, A. Meetsma andS. Gambarotta
Preparation and Characterization of [V3Cl5(TMEDA)3][V(NPh2)4]: a V(II)- V(III) [TMEDA = N,N,N'.N'-tetramethylethylenediamine] Mixed Valence Complex
J. Chem. Soc. Chem. Commun. 1990, 951
74. J.J.H. Edema, S. Gambarotta
Short and supershort Cr-Cr distances: a vanishing borderline between metal-metal bonds, magnetic couplings and ligand artifacts
Comm. Inorg. Chem.1991, 4, 195
75. J.J.H.Edema, S. Gambarotta, R. Duchateau, R. Haynes, E. Gabe
Novel titanium(II) amine complexes L4TiCl2[L = 1/2 TMEDA, 1/2 N,N,N'-trimethylethylenediamine, pyridine, 2,2'-bipyridine): synthesis and crystal structure of the monomeric trans-(TMEDA)2TiCl2
Inorg. Chem.1991, 30, 154
76. J.J.H.Edema, S.Gambarotta, A.L.Spek, W.J.J.Smeets
Polymetallic Chromium alkoxides: synthesis and crystal structures of (i-PrO)8Cr2Na4(THF)4and (µ3-OPh)10Cr4(µ3-O)3Na4(TMEDA)4
Inorg. Chem. 1991, 30, 1380
77. J J.H. Edema, S. Gambarotta, A. Meetsma, A. L. Spek, N. Veldman.
Synthesis and structural features of novel V(II) amides. The X-ray structures of the octahedral [(2-C5H4N)(CH3)N]2V[TMEDA] [TMEDA = N,N,N',N'-tetramethyl- ethylenediamine] and the square-pyramidal [2,5-(CH3)2C4H2N]2V[pyridine]3.
Inorg. Chem. 1991, 30, 1380
78. J.J.H. Edema, A. Meetsma, F. Van Bolhuis,S. Gambarotta
Role of the ligand in the formation of short vanadium-vanadium contacts. Preparation and crystal structure of monomeric {[(Ph2P)2CH]3V}[Li(THF)4] (THF)2and [PhNC(H)NPh]2V(TMEDA) and dimeric {[PhNC(Me)O]2V}2(TMEDA).
Inorg. Chem. 1991, 30, 2056
79. J.J. Edema,S. Gambarotta, C. Bensimon
Linear trimeric and monomeric octahedral V(II) diphenylacetate.
Inorg. Chem. 1991, 30, 2584
80. J.J. Edema, R. Duchateau, S.Gambarotta,C. Bensimon
Labile trivanadium and trititanium triangular clusters
Inorg. Chem. 1991, 30, 3585
81. J.J.H. Edema, A. Meetsma, S. Gambarotta, S.I. Khan, W.J.J. Smeets, A.L. Spek
Ligand and alkali metal cation control on the molecular complexity of anionic Chromium(II) aryloxides. Preparation and crystal structure of dimeric (PhO)10Cr2Li6(THF)6and (2,6-Me2C6H3O)6Cr2Li2(THF)4and trimeric (GuO)14Cr3Na9Cl with an encapsulated chloride ion.
Inorg. Chem. 1991, 30, 3639
82. R. Duchateau, A. Williams, S.Gambarotta, M.Y. Chiang.
Carbon-carbon double bond formation in the intermolecular acetonitrile reductive coupling promoted by a mononuclear Ti(II) compound. Preparation and characterization of two Ti(IV) imido compounds.
Inorg.Chem. 1991, 30, 4863.
83. Y. Wielstra, R. Duchateau, S. Gambarotta, C. Bensimon, E. Gabe
Binuclear zirconium fulvalene tetraallyl complex. The preparation and crystal structure of [h5:h5-C10H8][CpZr(h1-CH2CHCH2)(h3-CH2CHCH2)]2
J. Organomet. Chem. 1991, 418, 183
84. R. Duchateau, S. Gambarotta, N. Beydhoun, C. Bensimon
Side-on versus End-on coordination of dinitrogen to titanium(II) and mixed-valence titanium(I)/titanium(II) amido complexes
J. Am. Chem. Soc. 1991, 113, 8986
85. N. Beydoun, R. Duchateau, S. Gambarotta
Synthesis and characterization of a thermally robust titanium dinitrogen complex
J. Chem. Soc., Chem. Commun. 1992, 244
86. S. Hao, J.J.H. Edema, S. Gambarotta, C. Bensimon
Cr-Cr multiple bond reversible cleavage in [TAACr]2
Inorg. Chem. 1992, 31, 2676
87. S. Hao,S. Gambarotta, C. Bensimon
Reversible Cleavage of the Cr-Cr quadruple bond of [Me8Cr2][LiTHF]4via modification of the coordination sphere of the alkali cation. The preparation and the crystal structure of the monomeric [Me4Cr][LiTMEDA]2.
J. Am. Chem. Soc. 1992, 114, 3556
88. J.J. Edema, S. Gambarotta, A. Meetsma, A.L. Spek
Dimeric and monomeric chromium (II) and monomeric chromium (III) aryls. The crystal structure of the pyramidal Mz2Cr(py) [Mz = 0-Me2NCH2C6H4, py = pyridine], dimeric [(Me2NC6H4)2Cr and octahedral (Me2NC6H4)3Cr.
Organometallics1992, 11, 2452
89. R. Duchateau, R. Minhas, S. Gambarotta, C. Bensimon
Linear trimeric, dimeric and monomeric titanium(III) aryloxides
Inorg. Chem. 1992, 31, 4933.
90. J.J.H. Edema, S. Gambarotta, A. Meetsma, A.L. Spek, W.J.J. Smeets, M.Y. Chiang
Cr(II) amides: synthesis and structures
J. Chem. Soc., Dalton Trans. 1993, 789
91. David, G. Dick, Jilles, J.H. Edema, Robbert Duchateau, Sandro Gambarotta
Novel bis-trimethylsilylbenzamidinate Ti(III) complexes. The preparation and the crystal structures of {PhC[(Me3Si)N]2}2Ti(µ-Cl)2Li(TMEDA),{PhC[(Me3Si)N]2Ti(BH4) and {PhC[(Me3Si)N]2}2Ti(h3-allyl).
Inorg. Chem. 1993, 32, 1959
92. R.K. Minhas, J.J. Edema, S. Gambarotta
Vanadium (II) aryloxides
J. Am. Chem. Soc. 1993, 115, 6710
93. S. Hao,S. Gambarotta, C. Bensimon, J. Edema
Ligand steric bulk: a neglected factor in the formation of Cr-Cr supershort contacts.
Inorg. Chim. Acta Topical Volume (invited) 1993, 213, 65
94. S. Gambarotta, R. Minhas, J.J.H. Edema
Isolation and characterization of a vanadium ethylidyne complex. The crystal structure of [(Cy2N)2V]2Li(µ3-O)(µ2,h1:h1-CCH3): an unusual V2LiO cluster.
J. Chem. Soc. Chem. Commun. 1993, 1503
95. J. Jubb, S. Gambarotta
Preparation and characterization of the first vanadium Ynolate complex
J. Am. Chem. Soc. 1993, 115, 10410
96. A.L. Spek, J.J.H. Edema, S. Gambarotta
Chlorobis{2-[dimethylamino)methyl]-phenyl-C1,N}-(pyridine)vanadium (III)
Acta Cryst. 1994, C50, 1209
97. S. Hao, J-I. Song, P. Berno, S. Gambarotta
Cr(II) Organochromates. Preparation, Characterization and Stability
Organometallics1994, 13, 1326
98. S. Hao, J.I. Song, H. Aghabozorg, S. Gambarotta
Diphenylphosphinomethanide Complexes of Cr(II) and Sm(III): Preparation and Characterization of the Dinuclear [Cr(Ph2PC(H)PPh2)2](µ-Cl)[µ-C(H)(PPh2)2][Cr-(Ph2PC(H)PPh2)] and Mononuclear Pseudo-allylic Sm[h3-Ph2PC(H)PPh2]3.
J. Chem. Soc. Chem. Commun. 1994, 157.
99. P. Berno, R. Minhas, S. Hao, S. Gambarotta.
Preparation, Characterization and Reactivity of Binuclear V(III) {[(Me3Si)2N]V [µ-CH2SiMe2N(SiMe3)]}2. C-H s-Bond Metathesis Promoted by an Amido Function.
Organometallics1994, 13, 1052
100. J. Jubb, S. Gambarotta
The surprising role of THF in vanadium macrocyclic chemistry
Inorg. Chem. 1994, 33, 2503
101. J. Jubb, S. Gambarotta
Dinitrogen Reduction Operated by a Sm Macrocyclic Complex. Encapsulation of Dinitrogen into a Sm2Li4Metallic Cage.
J. Am. Chem. Soc. 1994, 116, 4477
102. P. Berno, S. Gambarotta
Reactivity of a four-membered vanadacycle ring supported by bulky silazanate ligand.
Organometallics1994, 13, 2569
103. J.-I. Song, P. B. and S. Gambarotta
Dinitrogen Fixation, Ligand Dehydrogenation and Cyclometallation in the Chemistry of V(III) Amides
J. Am. Chem. Soc.1994, 116, 6927
104. P. Berno, S. Hao, R. Minhas, S. Gambarotta
Dinitrogen Fixation versus Metal-Metal bond Formation in the Chemistry of V(II) Amidinates
J. Am. Chem. Soc. 1994, 116, 7417
105. P. Berno and S. Gambarotta
Insertion versus Elimination in the reaction of t-BuNC with a vanadacyclobutane ring supported by hexamethylsilazanate ligand
J. Chem. Soc. Chem. Commun. 1994, 2419
106. L. Scoles, R. Minhas, R. Duchateau, J. Jubb and S. Gambarotta
Synthesis and characterization of Novel Titanium (III) and (IV) Alkyls and Carbenes supported by Amide Ligands. The crystal structure of [(Cy2N)2Ti(µ-CH2)]2.
Organometallics1994, 13, 4978
107. J. Jubb, S. Gambarotta, R. Duchateau and J. H. Teuben
Different Fragmentation Pathways of THF Promoted by a Yttrium Macrocyclic Complex
J. Chem. Soc. Chem. Commun. 1994, 2641.
108. P. Berno, S. Gambarotta
Hydrogenolysis of the V-N Bond of a Vanadium(III) Amide: Isolation and Characterization of a Polynuclear Polyhydride/Nitride Mixed-Valence Complex.
Angew. Chem. Int. Ed. Engl. 1995, 34, 822
109. S. Hao, M. Dionne and S. Gambarotta
Preparation and Characterization of a New Series of Cr(II) Tetrahydroborates.
Can J. Chem.,Special Volume in honor of W. Graham (invited)1995, 73, 1126
110. L. Scoles and S. Gambarotta
Titanium Borohydrides Supported by Amide Ligands
Inorg. Chim. Acta, Croatto Memorial Volume (invited). 1995, 235, 375
111. P. Berno and S Gambarotta
Formation of Metallaziridine Ring and Dinitrogen Fixation Promoted by a Niobium Amide Complex
Organometallics1995, 14, 2159
112. J. Jubb, P. Berno, S. Hao and S. Gambarotta
The Presence of an Octahedral Carbon Atom in a Non-Solvated Tetralithium Macrocyclic Complex.
Inorg. Chem.1995, 34, 3563
113. S. Gambarotta
Dinitrogen Activation/Fixation 30 Years Later: a Puzzle still Unsolved
J. Organomet. Chem. (vol 500 invited review) 1995, 500, 117
114. J. Song and S. Gambarotta
Preparation and Characterization of a Dinuclear Low-valent Samarium Complex with a Short Sm-Sm Contact.
Angew. Chem. Int. Ed. Engl.1995, 34, 2141
115. P. Berno, H. Jenkins, S. Gambarotta, J. Blixt, G. A. Facey and C. Detellier.
The Isolation of [Ti(µ-CH3)5(µ-CH2)][(TMEDA)Li]3.THF: an Unusual and Highly Fluxional Titanium Organometallic Compound.
Angew. Chem. Int. Ed. Engl. 1995, 34, 2264
116. R. Minhas, L. Scoles, S. Wong and S. Gambarotta
Tri- and Tetravalent Titanium Alkyls Supported by Organic Amides.
Organometallics1996, 15, 1113.
117. M. Dionne, J. Jubb, H. Jenkins, S. Wong andS. Gambarotta
One- versus two-electron reduction of N2O promoted by a divalent chromium macrocyclic complex
Inorg. Chem.1996,35, 1874
118. S.Hao, P.Berno, R. Minhas and Sandro Gambarotta
The role of the Ligand Steric Hindrance in Determining the Stability of Very Short V-V Contacts. Preparation and Characterization of a Series of V(II) and V(III) Amidinates.
Inorg. Chim. Acta 1996, 244, 37
119. J. Jubb, L. Scoles, H. Jenkins and S. Gambarotta
Formation of Bridiging Nitride Versus Terminal Oxovanadium Promoted by a Low-valent Vanadium Macrocyclic Complex.
Chemistry. European J.l 1996, 2,767
120. R. Minhas, J. Song, Y. Ma and S. Gambarotta
Sm(II) and Sm(III) amides
Inorg. Chem. 1996,35, 1866
121 P. Berno,S. Gambarotta, S. Kotila and G. Erker
Novel Vanadium and Titanium Phosphorus Ylide Complexes
J. Chem. Soc. Chem. Commun. 1996, 779
122. L. Scoles, K. B. Ruppa, S. Gambarotta
Preparation of the First Ditantalum (III) Complex Containing a Ta-Ta Bond Without Bridging Ligands.
J. Am. Chem. Soc. 1996, 118, 2529
123. S. Hao, P. Berno, R. Minhas, S. Gambarotta
The role of the ligand steric hindrance in determining the stability of very short V-V contacts.
Inorg. Chim. Acta1996, 244, 37
124. N. Desmangles, H. Jenkins, K., Ruppa, S. Gambarotta
Preparation and characterization of a vanadium (III) dinitrogen complex supported by tripodal amide ligand.
Inorg. Chim. Acta(invited) 1996, 250, 1
125. P. Berno, M. Moore, R. ,Minhas and S Gambarotta
Monomeric and dimeric V(III) complexes supported by organic amides
Can. J. Chem.(invited) 1996, 74, 1052
126. J. Song, S. Gambarotta
Preparation and characterization of a diamaagnetic vanadium nitride
Chemistry, Eur. J.1996, 2, 1258
127. Kamalesh B.P. Ruppa, Natalie Desmangles, Sandro Gambarotta, Glenn Yap and Arnold L. Rheingold
Preparation and Characterization of a Homoleptic Vanadium(III) Amide Complex and its Transformation into Terminal Chalcogenide Derivatives [(3,5-Me2Ph) AdN]3V(=E) [E = S, Se; Ad = adamantyl].
Inorg. Chem. 1997, 36, 1194
128. Mark Moore, Sandro Gambarotta and Corinne Bensimon
Serendipitous Formation of a Dinuclear Vanadium(III) Amide Complex Containing a Vanadaazacyclobutane Ring. Potassium-H Agostic Interactions Holding Together a V2K2Tetrametallic Framework
Organometallics1997, 16, 1086
129. Mark Moore, Sandro Gambarotta, Glenn Yap, Louise M. Liable-Sands and Arnold Rheingold
Formation of a Vanadium(V) Bicyclic Carbene/Amide Complex via Insertion of Alkyne into a V-C Bond.
J. Chem. Soc. Chem. Commun. 1997, 643
130. Shoukang Hao, Khalil Feghali and Sandro Gambarotta
Preparation and Characterization of a Diamagnetic and Dinuclear Titanium(III) Formamidinate Complex. Evidence for the Existence of a Ti-Ti Bond?
Inorg. Chem. 1997¸36, 1745
131. Mark Moore, Khalil Feghali and Sandro Gambarotta
Preparation and Characterization of a Diamagnetic Sulfido-Bridged Divanadium Amide Complex.
Inorg. Chem. 1997¸36, 2191
132. Damien Reardon, Istvan Kovacs, Kamalesh B.P. Ruppa, Khalil Feghali, Sandro Gambarottaand Jeffrey Petersen
Reactivity of Coordinatively Unsaturated Trivalent Chromium Complexes with Sulfur. Preparation of Novel Sulfide-Bridged Dinuclear Cr(IV) Derivatives.
Chemistry, Eur. J. 1997, 3, 1482
133. Aparna Kasani, Sandro Gambarottaand Corinne Bensimon
Zirconium alkyl and borohydride complexes stabilized by a sterically demanding anionic organic amide. Thecrystal structures of ZrMeL3(2) and Zr(BH4)L3(3) [L = (3,5-Me2Ph)N(Ad), Ad = adamantyl].
Can. J. Chem. (in honor of B. Conway) 1997,75, 1494
134. Maryam Tayebani, Khalil Feghali, Sandro Gambarottaand Corinne Bensimon
The reduction of Nb2Cl6(TMEDA)2by Liamide
J. Chem. Soc. Chem. Commun. 1997, 2001
135. Natalie Desmangles, Sandro Gambarotta, Corinne Bensimon, Stephen Davis and Hayder ZahalkaPreparation and Characterization of (R2N)2VCl2[R = Cy, i-Pr] and its Activity as Olefin Polymerization Catalyst.
J. Organomet. Chem. (special edition in honor of Bruce King), 1997, 562, 53,
136. Maryam Tayebani, Khalil Feghali, Sandro Gambarotta, and Corinne Bensimon
Amide C-N bond cleavage and formation of nitride promoted by a Nb(II) cluster.
Organometallics1997, 16, 5084
137. Kamalesh B.P. Ruppa,Khalil Feghali, Istvan Kovacs, Kasani Aparna, Sandro Gambarotta, Glenn P.A. Yap and Corinne Bensimon
The reaction of di- and trivalent chromium amides with O2.
J. Chem. Soc. Dalton Trans. 1998, 1595.
138. Kamalesh B. P. Ruppa, Sandro Gambarottaand Glenn P.A. Yap
Tetravalent Niobium Alkyls and Enolate Stabilized by Anionic Organic Amides.
Inorg. Chim. Acta(special edition in honor of Vol’pin) 1998,280, 143.
139. Maryam Tayebani, Khalil Feghali, Sandro Gambarotta, and Glenn Yap
Dinuclear Oxidative Addition of Low-valent Nb Amide to a Ligand C-H bond.
Organometallics 1998,17, 4282
140. Maryam Tayebani, Sandro Gambarottaand Glenn Yap
C-H versus C-N bond cleavage promoted by Nb(II) amide.
Organometallics1998, 17, 3639.
141. Tiffany Dubé, Sandro Gambarotta, and Glenn Yap
Preparation and reactivity of a compartmental Schiff base samarium dinuclear complex.
Organometallics 1998,17, 3967
142. Maryam Tayebani, Sandro Gambarottaand Glenn Yap
Pyrrole denitrogenation and TMEDA fragmentation promoted by a Nb(II) cluster
Angew. Chem. Int. Ed. Engl.1998, 3002 (cited by C&En )
143. Aparna KasaniaRuppa P. Kamalesh Babu, Sandro Gambarotta and Glenn P. Yap
Novel Mn(III) and Mn(IV) oxo clusters. Synthesis and Characterization of manganese formamidinate complexes and their reaction with dioxygen.
Chemistry,
Eur. J. 1999, 5, 577.
144. Tiffany Dube’, Sandro Gambarotta, Glenn Yap
Reversible fixation of ethylene on a Sm(II) calix-pyrrole complex.
Angew. Chem. Int. Ed. Engl. 1999, 38, 1432.
145. Damien Reardon, Françoise Conan, Sandro Gambarotta, Glenn Yap, Qinyan Wang
Life and Death of an Active Ethylene Polymerization Catalyst. Ligand Involvement in Catalyst Activation and Deactivation. Isolation and Characterization of two Unprecedented Neutral and Anionic Vanadium (I) Alkyls.
J. Am. Chem. Soc. 1999, 121, 9318.
146. Maryam Tayebani, Khalil Feghali, Sandro Gambarotta, Glenn Yap and Laurence Thompson
Preparation and characterization of a paramagnetic diniobium complex with very short Nb-Nb distance: evidence for a pseudo Nb-Nb triple bond?
Angew. Chem. Int. Ed. Engl. 1999, 38,3659.
147. Yinlin Ma, Damien Reardon, Sandro Gambarotta, Glenn Yap, Hayder Zahalka and Catherine Lemay
Vanadium Catalyzed Ethylene-Propylene Copolymerization: the Question of the Metal Oxidation State in Ziegler-Natta Polymerization Promoted by (b-diketonate)3V.
Organometallics 1999, 18, 2773.
148. Tiffany Dube', Sabrina Conoci, Sandro Gambarotta, Glenn Yap and Giuseppe Vasapollo
Tetrametallic reduction of dinitrogen: formation of a tetranuclear samarium dinitrogen cluster.
Angew. Chem. Int. Ed. Engl1999, 38, 3657.
149. Tiffany Dubé, Sandro Gambarotta, Glenn P. A. Yap
Dinuclear Complexes of Di-, Tri- and Mixed-Valent Samarium Supported by the Calix-tetrapyrrole Ligand.
Organometallics2000, 19, 817.
150. Tiffany Dubé, Sabrina Conoci, Sandro Gambarotta, Glenn P. A. Yap
Divalent and Mixed-Valence Samarium Clusters Supported by Dipyrrolide Ligand.
Organometallics2000, 19, 1182
151. Tiffany Dube, Dominique Freckmann, Sabrina Conoci, Sandro Gambarotta and Glenn P. A. Yap
Monomeric and Octameric Divalent Ytterbium Complexes of Diphenylmethyl Dipyrrolyl Dianion.
Organometallics2000, 19, 209.
152. Tiffany Dubé, Sandro Gambarotta, Glenn P.A. Yap, Sabrina Conoci
Preparation and Characterization of two Mixed-valence Samarium Octameric Clusters
Organometallics2000, 19, 115.
153. Tiffany Dubé, Sandro Gambarotta and Glenn Yap
Samarium hydride, methyl and vinyl complexes supported by calix-tetrapyrrole ring macrocycle. Thermal decomposition to Sm(II)
Organometallics2000, 19, 121.
154 Tiffany Dubé, Sabrina Conoci, Sandro Gambarotta, Glenn P.A. Yap
Tetrametallic Divalent Samarium Cluster Hydride and Dinitrogen Complex.
Organometallics2000,19,3716
156. Jingwen Guan, Tiffany Dubé, Sandro Gambarotta and Glenn P.A. Yap
Dinitrogen Labile Coordination versus Four-Electron Reduction, THF Cleavage and Fragmentation Promoted by a (calix-tetrapyrrole)Sm(II) Complex.
Organometallics2000, 19, 4820.
157. Maryam Tayebani, Sabrina Conoci, Khalil Feghali, Sandro Gambarotta and Glenn P.A. Yap
Tri-, tetra- and mixed-valent niobium complexes supported by a tripodal tri-pyrrolylmethane trianion.
Organometallics2000,19,4568
158. Mani Ganesan, Mathieu P. Lalonde, Sandro Gambarotta, Glenn, P. A. Yap
Isolation and characterization of linear polymeric {[(1,1-H10C6(a-C4H3N)2]2Sm[Na (THF)]2}n: a 30 electron species with a (h5-Cp)4Ln type structure.
Organometallics2001, 20, 2443.
159 Ghazar Aharonian, Khalil Feghali, Sandro Gambarotta and Glenn P. A. Yap
Stability of Trivalent Vanadium Alkyl and Hydride Supported by a Chelating Phosphinimido Ligand.
Organometallics2001, 20, 2616.
160. Maryam Tayebani, Khalil Feghali, Sandro Gambarotta, Glenn Yap
Insensitivity of the Nb-Nb distance in the a paddle-wheel compound to bond multiplicity and axial ligation
Inorg. Chem.2001, 1399.
Maryam Tayebani, Ghazar Aharonian, Khalil feghali, Sandro Gambarotta, Glenn Yap
Preparation and characterization of a tetranuclear and mixed-valence Nb(II)/Nb(III) diamagnetic Nb4Cl12Li2(THF)8cluster
Inorg. Chem.2001, 2442.
162. Ilia Korobkov. Sandro Gambarotta, Glenn P. A. Yap
Highly Reactive U(III) Polypyrrolide Complexes: Intramolecular C-H Bond Activation, Ligand Isomerization and Solvent Deoxygenation and Fragmentation
Organometallics2001, 20, 2552.
163. Mani Ganesan, Sandro Gambarotta, Glenn P. A. Yap
Highly reactive Sm[II] macrocyclic clusters precursors to N2reduction.
Angew. Chem. Int. Ed. Engl. 2001, 113, 788.
164. Tiffany Dubé, Jingwen Guan, Sandro Gambarotta, Glenn P. A. Yap
Reactivity of calix-tetrapyrrole SmIIand SmIIIcomplexes with acetylene: Isolation of an "N-confused" calix-tetrapyrrole ring.
Chem. Eur. J., 2001, 7,374.
Ilia Korobkov. Sandro Gambarotta, Glenn P. A. Yap, Lawrence, Thompson, Jeffrey Hay
Dinuclear Tri- and mixed-valence uranium [(-CH2-)5]4-calix -[4]-tetrapyrrole complexes with short intermetallic distances.Organometallics, 2001,20, 5440
166. Ghazar Aharonian, Sandro Gambarotta*and Glenn P. A. Yap
Oxidative Addition of a Dinuclear and Divalent Vanadium Hydride to an Olefin C-H Bond Leading to Catalytic Hydrogenation. Organometallics,2001,20, 5008.
167. Sandro Gambarotta
Using Dinitrogen as a Raw Material: There is a Future?
Inorg. Chem. Highlights, G. Meyer, D. Naumann, L. Wesemann Eds.; Wiley-VCH: Weinheim 2002
168. Dominique M. M. Freckmann, Tiffany Dubé, Christian D. Bérubé, Sandro Gambarotta, Glenn P. A. Yap.
Cyclic Di- and Mixed-valent Yb Complexes Supported by Dipyrrolide Ligands.
Organometallics, , 2002,21, 1240.
169. Khalil Feghali, David J. Harding, Damien Reardon, Sandro Gambarotta, Glenn Yap.
Stability of Metal-Carbon Bond versusMetal Reduction During Ethylene Polymerization Promoted by a Vanadium Complex: the Role of the Aluminum Cocatalyst.
Organometallics, 2002,21, 968.
170. Damien Reardon, Ghazar Aharonian, Sandro Gambarotta, Glenn P. A. Yap
Mono- and zerovalent Mn alkyl complexes supported by the a,a'-diiminato pyridine ligand: alkyl stabilization at the expenses of catalytic performance.
Organometallics2002, 21, 786
171. Ilia Korobkov, Ghazar Aharonian, Sandro Gambarotta, Glenn, P. A. Yap
Ligand fragmentation promoted by a transient low-valent thulium.
Organometallics2002, 21, 4899
172. David Enright, Sandro Gambarotta, Glenn, P. A. Yap and Peter H. M. Budzelaar
The ability of the a,a-diimine pyridine ligand system to accept negative charge: isolation of paramagnetic and diamagnetic trianions
Angew. Chem. Int. Ed. Engl. 2002,41, 3873.
173. Ghazar Aharonian, Sandro Gambarotta and Glenn P. A. Yap
Tantalum complexes of diphenyldipyrrolide dianion: partial hydrogenation of a phenyl ring.
Organometallics2002, 21, 4257.
174. Damien Reardon, Jingwen Guan, Sandro Gambarotta, Glenn, P. A. Yap, David R. Wilson
Vanadium-promoted aldol condensation and pinacolic coupling of acetylpyrrole: Formation of two new potent dinuclear catalysts for olefin copolymerization.
Organometallics2002, 21, 4390.
175. Hiroyasu Sugiyama, Ghazar Aharonian, Sandro Gambarotta,* Glenn P. A. Yap, Peter H.M. Budzelaar
The participation of the a,a’-di-imino pyridine ligand system to reduction of the metal center during alkylation.
J. Am. Chem. Soc. 2002,124,12268.
176. IliaKorobkov, Sandro Gambarotta*, Glenn P. A. Yap
Highly Reactive Uranium Complex Supported by the Calix-[4]-tetrapyrrole Tetra-Anion Affording Dinitrogen Cleavage, Solvent Deoxygenation and Polysilanol Depolymerization.**
Angew. Chem. Int. Ed. Engl. 2002,41, 3433.
177. Carola Schulzke, Dave Enright, Hiroyasu Sugiyama, Guy LeBlanc, Sandro Gambarotta,* Glenn P. A. Yap, Laurence K. Thompson,David R. Wilson,Rob Duchateau
The Unusual Stability of Homoleptic Di- and Tetra-valent Cr alkyls.
Organometallics2002, 21, 3810
178. Ilia Korobkov, Sandro Gambarotta, Glenn, P. A. Yap
Reversible alkylation at the pyridine nitrogen in a a,a-diimine pyridine ligand system.
Organometallics,2002,21, 3088.
Mani Ganesan, Christian D. Bérubé, Sandro Gambarotta, Glenn P. A. Yap
The Effect of the Alkali Cation on the Bonding Mode of 2,5-Dimethylpyrrole in Divalent Samarium and Ytterbium Complexes.
Organometallics,2002, 21, 1707
180. Patrick Crewdson, Sandro Gambarotta, Glenn Yap, and Laurence K. Thompson
Dinuclear and octanuclear Mn(II) complexes with μ2-C,μ2-N(pyrrolide) and μ-h1:h5-(pyrrolide) bridges: a structural and magnetic study.
Inorg. Chem. 2003, 42, 8579
181. Ilia Korobkov, S. Gambarotta
Amide from dinitrogen via in situcleavage and partial hydrogenation promoted by a transient zero-valent thorium synthon: an unprecedented transformation
Angew. Chem. Int. Ed. Engl.(V.I.P.section) 200342, 4958 Cited by C&En
182. Christian D. Bérubé, Sandro Gambarotta, Glenn P. A. Yap
Serendipitous isolation of the first example of a mixed-valence samarium tripyrrane complex
Organometallics 2003, 22, 3742.
183. Jennifer Scott, Sandro Gambarotta, Glenn Yap, Denis G. Rancourt
Labile tetranuclear Fe(II) and Co(II) clusters of a dipyrrolide dianion with two diamagnetic ferrous links.
Organometallics2003,22, 2352.
184. Christian D. Bérubé, Sandro Gambarotta, Glenn P. A. Yap
Di- and Trivalent Dinuclear Samarium Complexes Supported by Pyrrole-based tetradentate Schiff-Base
Organometallics 2003, 22, 434.
185. IliaKorobkov, Sandro Gambarotta, Glenn P. A. Yap
The first thorium arene complex: a divalent synthon
Angew. Chem. Int. Ed. Engl 2003, 42, 814.Cited by C&En
186. Sandro Gambarotta
Vanadium-Based Ziegler-Natta: Challenges, Promises, Problems.
Coordination Chemistry Reviews 2003, 237, 229
187 Ilia Korobkov, Athimoolan Arunachalampillai and Sandro Gambarotta
Cyclometallation and solvent deoxygenation during reduction of a homoleptic Th(OAr)4complex: serendipitous formation of a terminally bonded Th-OH function.
Organometallics2004, 23, 6248.
188 S. Gambarotta, I. Korobkov
cis- Double Addition of CO2to a Coordinated Arene of a Thorium Complex.
Organometallics2004,23, 5379
189. H. Sugiyama, S. Gambarotta, G. P. A. Yap, D. R. Wilson, S. K.-H. Thiele
Preparation of an active Nd catalyst for regioselective butadiene cis-polymerization supported by a dianionic modification of the 2,6-diiminopyridine ligand
Organometallics2004,23, 5054
190. Hiroyasu Sugiyama, Ilia Korobkov, Sandro Gambarotta, Angela Möller, Peter H.M. Budzelaar
Preparation, characterization and magnetic behavior of the Ln derivatives (Ln = Nd, La) of a 2,6-diiminepyridine ligand and corresponding di-anion.
Inorg. Chem. 2004, 43, 5771
191. H. Gao, I. Korobkov, S. Gambarotta
Divalent molybdenum complexes of the dipyrrolide ligand system. Isolation of a Mo2unit with a 45° twist angle.
Inorg. Chem. 2004,43, 1108
192 Jennifer Scott, Sandro Gambarotta
Multimetallic cooperative activation of N2
Angew. Chem. Int. Ed. Engl.2004, 43, 5298
193. Jennifer Scott, Sandro Gambarotta, Ilia Korobkov and Peter Budzelaar
Reduction of bis-iminopyridineFe: evidence for a non-cationic polymerization pathway?
Organometallics 2005,24, 6298.
194. Jennifer Scott, Sandro Gambarotta,*Ilia Korobkov, Q. Knijnenburg, Bas de Bruin and Peter Budzelaar
Formation of a paramagnetic Al complex and extrusion of Fe during the reaction of (diiminepyridine)Fe with AlR3(R = Me, Et).
J. Am. Chem. Soc. 2005, 127, 17204.
195. Patrick Crewdson, Sandro Gambarotta, Marie-Charlotte Djoman, Ilia Korobkov, Robbert Duchateau
Switchable Cr(II) Ethylene Oligomerization/Polymerization Catalyst
Organometallics 2005, 24, 5214.
196. Jennifer Scott, Sandro Gambarotta, Ilia Korobkovand Peter H.M. Budzelaar
Metal versusligand alkylation in the reactivity of the (bis-iminopyridinato)Fe catalyst
J. Am. Chem. Soc. 2005, 127, 13019.
197. Arunachalampillai Athimoolam, Sandro Gambarotta* and Ilia Korobkov
Preparation, Characterization and Structure of two Dipyrrolide Thorium Homoleptic Complexes: Isolation of a Dipyrrolide Dipotassium Salt with an Inverted-Sandwich Type of Structure.
Can. J. Chem. (special issue dedicated to H. Alper)2005, 83, 832.
198. Arunachalampillai Athimoolam, Sandro Gambarotta and Ilia Korobkov
Ligand metallation during the reduction of a Th(IV) amide complex
Organometallics 2005, 24, 1996.
199. Indu Vidyaratne , Sandro Gambarotta , Ilia Korobkov , Peter H. M. Budzelaar
Dinitrogen Partial Reduction by Formally Zero- and Divalent Vanadium Complexes Supported by the Bis-iminopyridine System
Inorganic Chemistry2005, 44, 1187
200. J. Scott, S. Gambarotta, I. Korobkov
Ligand-assisted reduction of Co(II) to Co(I) and subsequent fixation of dinitrogen
Can. J. Chem. (special issue dedicated to N2fixation) 2005, 83, 279.
201 S. Gambarotta, I. Korobkov
Trivalent Uranium
Progress in Inorg. Chem. 2005, 54, ch-4
202. Knijnenburg, Q.; Gambarotta, S.; Budzelaar, P.H.M.
Ligand-centred reactivity in diiminepyridine complexes
Dalton Trans. 2006, 5442 .
203. Claire Temple, Amir Jabri, Pat Crewdson, Sandro Gambarotta, Ilia Korobkov
The Question of the Cr Oxidation State in the (SNS)Cr [(SNS) = CySCH2CH2N(H)CH2CH2SCy] Catalyst for Selective Ethylene Trimerization: An Unanticipated Re-oxidation Pathway.
Angew. Chem. Int. Ed. Engl. 2006,45, 7050
204 Harminder Phull, Davide Alberti, Ilia Korobkov, Sandro Gambarotta
Fixation of CO2by magnesium cations: a re-interpretation
Angew. Chem. Int. Ed. Engl. (HOT papers section) 2006, 45, 5331
205. Athimoolam Arunachalampillai, Patrick Crewdson, Ilia Korobkov and Sandro Gambarotta
Ring opening, C-O and C-N bond cleavage by transient reduced Th species.
Organometallics, 2006,25, 3856
206. Amir Jabri, Claire Temple, Patrick Crewdson, Sandro Gambarotta, Ilia Korobkov, Robbert Duchateau
Role of the metal oxidation state in the SNS-Cr catalyst for ethylene trimerization. Isolation of di- and trivalent cationic intermediates.
J. Am. Chem. Soc.2006,128, 9238
207. Amir Jabri, Patrick Crewdson, Sandro Gambarotta, Ilia Korobkov
Isolation of a cationic Cr(II) species in a catalytic system for ethylene tri- and tetramerization
Organometallics2006, 25, 715
208. Indu Vidyaratne, Jennifer Scott, Sandro Gambarotta, Peter Budzelaar
Multiple pathways of dinitrogen activation during the reduction of a Fe bis-imino pyridine complex
Inorg. Chem. Accepted
209. Indu Vidyaratne, Patrick Crewdson, Emeric Lefebvre, Sandro Gambarotta
Dinitrogen Coordination and Cleavage Promoted by a Vanadium Complex of a s,p,s- Donor Ligand.
Inorg. Chem. in press
210. P.G. Cozzi, S. Gambarotta, M. Monatri, L. Zoli
Convenient preparation of chiral dipyrrolyl methanes.
Collect. Czech. Chem. Commun. 2007, 72, 1046 (invited) .
211. Indu Vidyaratne, Jennifer Scott, Sandro Gambarotta, Peter Budzelaar
Dinitrogen fixation, partial reduction and formation of coordinated imide promoted by a chromium bis-iminopyridine complex.
Inorg. Chem.2007, 46, 7040
212. Claire N. Temple, Sandro Gambarotta, Ilia Korobkov, Robbert Duchateau
New Insight into the Role of the Metal Oxidation State in Controlling the Selectivity of the Cr-(SNS) Ethylene Trimerization Catalyst
Organometallics2007,26, 4598
213. Amir Jabri, Ilia Korobkov, Sandro Gambarotta, Robbert Duchateau
Single-site, single-component catalysts for very high Mw polyethylene: a robust “ready-to-go” vanadium p-bonded complex without a pre-formed V-C bond.
Angew. Chem. Int. Ed.2007, 46, 6119.
214. Indu Vidyaratne, Jennifer Scott, Sandro Gambarotta and Robbert Duchateau
The reactivity of chromium complexes of a bis-iminopyridine ligand: highly active ethylene polymerization catalysts carrying the metal in a formally low oxidation state.
Organometallics2007,26, 3201.
215. Grigory B. Nikiforov, Patrick Crewdson, Sandro Gambarotta*, Ilia Korobkov and Peter, H. M. Budzelaar*
Reduction of Titanium supported by a s-/p-bonded Tripyrrole Ligand: Ligand C-N Bond Cleavage and Coordination of Olefin and Arene with an inverse Sandwich Structure.
Organometallics2007, 26, 48.
216. Indu Vidyaratne, Jennifer Scott, Sandro Gambarotta and Robbert Duchateau The reactivity of chromium complexes of a bis-iminopyridine ligand: highly active ethylene polymerization catalysts carrying the metal in a formally low oxidation state.
Organometallics2007, 26, 3201.
217. Amir Jabri, Ilia Korobkov, Sandro Gambarotta, Robbert Duchateau Single-site, single-component catalysts for very high Mw polyethylene: a robust “ready-to-go” vanadium p-bonded complex without a pre-formed V-C bond.
Angew. Chem. Int. Ed.2007, 46, 6119.
218. Claire N. Temple, Sandro Gambarotta, Ilia Korobkov, Robbert Duchateau
New Insight into the Role of the Metal Oxidation State in Controlling the Selectivity of the Cr-(SNS) Ethylene Trimerization Catalyst
Organometallics2007, 26, 4598
219. Indu Vidyaratne, Jennifer Scott, Sandro Gambarotta, Peter Budzelaar Dinitrogen fixation, partial reduction and formation of coordinated imide promoted by a chromium bis-iminopyridine complex.
Inorg. Chem.2007, 46, 7040
220. M. Monatri, L. Zoli, P.G. Cozzi, S. Gambarotta. Convenient preparation of chiral dipyrrolyl methanes.
Collect. Czech. Chem. Commun. 2007, 72, 1046 (invited) .
221 Indu Vidyaratne, Patrick Crewdson, Emeric Lefebvre, Sandro Gambarotta Dinitrogen Coordination and Cleavage Promoted by a Vanadium Complex of a ,, - Donor Ligand
Inorg. Chem. 2007, 46, 8836.
222. Indu Vidyaratne, Jennifer Scott, Sandro Gambarotta, Peter Budzelaar
Multiple pathways of dinitrogen activation during the reduction of a Fe bis-imino pyridine complex
Inorg. Chem. 2008, 47, 896 (most accessed article Jan-Apr 2008).
223. Sougandi Ilango, Balamurugan Vidjayacoumar, Sandro Gambarotta, Serge I. Gorelsky
Low-Valent Vanadium Complexes of a Pyrrolide-Based Ligand. Electronic Structure of a Dimeric V(I) complex with a Short and Weak Metal-Metal Bond.
Inorg. Chem. 2008, 47, 3265
224. Khalid Albahily, Ece Koç, Danya Al-Baldawi, Didier Savard, Sandro Gambarotta, Tara J. Burchell, Robbert Duchateau. Chromium Catalysts Supported by a non-Innocent NPN Ligand which Switch Activity from non- Selective Ethylene Oligomerization to Trimerization and Polymerization: Isolation of the First Single-Component Chromium Polymerization Catalysts.
Angew. Chem. Int. Ed. Engl. 2008, 47, 5816.
225. Khalid Albahily, Danya Al-Baldawi, Sandro Gambarotta, Robbert Duchateau, Ece Koç, Tara J. Burchell. Preparation and Characterization of a Switcheable Single-Component Chromium Trimerization Catalyst.
Organometallics2008, 27, 5943
226. Khalid Albahily, Danya Al-Baldawi, Sandro Gambarotta, Robbert Duchateau, Ece Koç, Tara J. Burchell. Isolation of a Chromium-HydrideSingle-Component Ethylene Polymerization Catalyst.
Organometallics2008, 27, 22.
227. Amir Jabri, Chris B. Mason,Yan Sim,Sandro Gambarotta, Tara J. Burchell,Robbert Duchateau.
Isolation of Single-Component Trimerization and Polymerization Chromium Catalysts: the Role of the Metal Oxidation State
Angew. Chem. Int. Ed. Engl.2008, 47, 9717 (cited on C&En)
228. Steven Horvath, Serge I. Gorelsky, Sandro Gambarotta, Ilia Korobkov Breaking the 1.80 Å Barrier of the Cr-Cr Multiple Bond Between Cr(II) Atoms.
Angew. Chem. Int. Ed. Engl.2008, 47, 9937.
229. Ilia Korobkov, Serge Gorelsky, Sandro Gambarotta Reduced uranium complexes: synthetic and DFT study on the role of p-ligation in the stabilization of uranium species in aformallow-valent state.
J. Am. Chem. Soc.2009, 131, 10406.
230. Ilia Korobkov, Sandro Gambarotta Aluminate Sm(II) and Sm(III) Aryloxides. Isolation of a Single-component Ethylene Polymerization CatalystOrganometallics2009, 28, 4009
231. Indu Vidyaratne, Grigory B. Nikiforov, Serge I. Gorelsky, Sandro Gambarotta, Robbert Duchateau, Ilia KorobkovIsolation of a self-activating ethylene trimerization catalyst
Angew. Chem. Int. Ed. Engl.2009, 48, 6552.
232. Grigory B. Nikiforov, Indu Vidyaratne, Sandro Gambarotta, Ilia Korobkov.
Titanium-Promoted Dinitrogen Cleavage Partial Hydrogenation and Silylation.
Angew. Chem. Int. Ed. Engl.2009, 48, 7415.
233. Ilia Korobkov and Sandro Gambarotta Unusual reactivity of a Tm-pyrrolide/aluminate complex with a metallocene-type of structural motif.
Organometallics 2009, 28,5560
234. Ilia Korobkov and Sandro Gambarotta Reducing the Irreducible: Preparation of a Rare Paramagnetic Thorium Species
Organometallics2010, 29 692
228. Ilia Korobkov and Sandro Gambarotta Ligand Metallation in the Reactivity of a Tetravalent Uranium Amide
Inorg. Chem. 2010, 49, 3409
235. Indira Thapa, Sandro Gambarotta,Robbert Duchateau, Shaneesh Vadake Kulangara and Reynald ChevalierSwitchable Chromium (II) Complexes of a Chelating Amidophosphine (N-P) for Ethylene Selective and non-Selective Oligomerization.
Organometallics2010, 29, 4080
236. Ilia Korobkov and Sandro Gambarotta Ligand Metallation in the Reactivity of a Tetravalent Uranium Amide
Inorg. Chem. 2010, 49, 3409
237. Sebastiano Licciulli, Indira Thapa, Khalid AlBahily, Ilia Korobkov, Sandro Gambarotta, Robbert Duchateau,Reynald Chevalier, Katrin Schuhen. Towards Selective Catalytic Ethylene Tetramerization.
Angew Chem. Int. Ed. Engl. 2010, 49, 9225∗
238. Sebastiano Licciulli, Khalid Albahily, Valeria Fomitcheva, Ilia Korobkov,Sandro GambarottaRobbert Duchateau. The first Chromium Ethylidene as a Potent Catalyst for Selective Ethylene Trimerization.
Angew Chem. Int. Ed. Engl. 2011,50, 2346
239.Khalid Albahily, Yacoob Shaikh, Elena Sebastiao, Sandro Gambarotta Ilia Korobkov and Serge I. GorelskyVinyl Oxidative Coupling as a Synthetic Route to Catalytically Active Monovalent Chromium
J. Am. Chem. Soc.2011, 133, 6388
240. Khalid Albahily, Valeria Fomitcheva, Sandro Gambarotta, Ilia KorobkovbMuralee Muruges and Serge I. GorelskyPreparation and Characterization of a Reduced Chromium Complex via Vinyl Oxidative Coupling: Formation of a Self-Activating Catalyst for Selective Ethylene Trimerization. J. Am. Chem. Soc 2011, 133, 6380
241. Di Zhu, Indira Thapa, Ilia Korobkov, Sandro Gambarotta, Peter H.M. Budzelaar. p-Acceptor ligands and organic radical chemistry Inorg. Chem.2011, 50, 9879.
242. Khalid Albahily,Sebastiano Licciulli, Sandro Gambarotta, Ilia Korobkov, Reynald Chevalier, Kathrine Schuhen, Robbert DuchateauHighly Active Ethylene Oligomerization Catalysts.
Organometallics2011, 30, 3346
243. Khalid Albahily, Valeria Fomitcheva, Yacoob Shaikh, Elena Sebastiao,Serge I. Gorelsky,Sandro Gambarotta, Ilia Korobkov, Robbet Duchateau. New Self-Activating Organochromium Catalyst Precursor for Selective Ethylene Trimerization
Organometallics 2011, 30, 4201.
244. Khalid Albahily,Yacoob Shaikh, Zeeshan Ahmed, Ilia Korobkov, Sandro Gambarotta, Robbert Duchateau Isolation of a Self-Activating EthyleneTrimerization Catalyst of a Cr-SNS System.
Organometallics 2011, 30, 4159
245. Khalid Albahily,Zeeshan Ahmed, Sandro Gambarotta, Ece Koç,Robbert Duchateau. Ilia Korobkov,
New Iminophosphonamide Chromium (II) Complexes as Highly Active Polymer-Free Ethylene Oligomerization Catalysts.
Organometallics 2011, 30, 6022
246. Khalid Albahily, Sandro Gambarotta, and Robbert Duchateau
Ethylene Oligomerization Promoted by a Silylated-SNS Chromium System
Organometallics 2011, 30, 4655.
247. Indira Thapa, Sandro Gambarotta, Ilia Korobkov.Muralee Murugesu and Peter Budzelaar
Isolation and Characterization of a Class-II Mixed-Valence Cr(I)/Cr(II) Self-Activating Ethylene Trimerization Catalyst.
Organometallics 2012, 31, 486
248. Yacoob Shaikh, Khalid Albahily, Matthew Sutcliffe, Valeria Fomitcheva, Sandro Gambarotta, Ilia Korobkov, Robbert Duchateau
AHighly Selective Ethylene Tetramerization Catalyst
Angew. Chem. Int. Ed. Engl 2012, 51, 1366.
249. Shaneesh Vadake Kulangara,Chris Mason, Michael Juba, Yung Yang, Indira Thapa, Sandro Gambarotta, Ilia Korobkov, Rob Duchateau
Synthesis and catalytic oligomerization activity of chromium catalysts of ligand systems with switchable connectivity.
Organometallics2012, 31, 6438
250. Shaneesh Vadake Kulangara, Amir Jabri, Yun Yang, Ilia Korobkov, Sandro Gambarotta, Rob Duchateau
Synthesis, X-ray Structural Analysis, and Ethylene Polymerization Studies of Group IV Metal Heterobimetallic Aluminum-Pyrrolyl Complexes
Organometallics 2012, 31, 6085
251. Yacoob Shaikh, Joanna Gurnham, Khalid Albahily, Sandro Gambarotta, Ilia Korobkov
"Aminophosphine-Based Chromium Catalysts for Selective Ethylene Tetramerization"
Organometallics 2012, 31, 7427
252. Vladimir Shuster, Sandro Gambarotta, Grigory B. Nikiforov, Ilia Korobkov and Peter H.M. Budzelaar.
Radical Cleavage of Al-C Bonds Promoted by Phenazine: from non-Innocent Ligand to Radical Abstractor.
Organometallics 2012,31, 7011.
253. Vladimir Shuster, Sandro Gambarotta, Grigory B. Nikiforov, Ilia Korobkov and Peter H.M. Budzelaar.
Organometallics2013, 32, 2329
254. Ahmed Alzamly, Sandro Gambarotta and Ilia Korobkov
Pyridine-Based Pincer PNP-Type of Polymer-Free Ethylene Oligomerization Using Ligand
Organometallics2013, 32, 7204
255. Ahmed Alzamly, Sandro Gambarotta and Ilia Korobkov
Synthesis, Structures, and Ethylene Oligomerization Activity of Bis(phosphanylamine)pyridine Chromium/Aluminate Complexes
Organometallics 2013, 32, 7107
256. Ahmed Alzamly, Serge I. Gorelsky,bSandro Gambarotta, Ilia Korobkov, Jennifer Le Roy, and Muralee Murugesu
Chromium-Chromium Interaction in a Binuclear Mixed Valent Chromium Cr(I)-Cr(II) Complex
Inorg. Chem. 2014, 53, 11492
257. Joanna Gurnham, Sandro Gambarotta, Ilia Korobkov,†Lidia Jasinska-Walc,and Robbert Duchateau.
Chromium Catalyzed CO2-Epoxide Copolymerization
Organometallics 2014,33, 4401
258. Ahmed Alzamly,; SandroGambarotta,; Ilia Korobkov,; Muralee Murugesu,; Peter Budzelaar,; Jennifer LeRoy,
Isolation of a Hexanuclear Chromium Cluster with a Tetrahedral Hydridic Core and its catalytic behavior for ethylene oligomerization
Inorg. Chem.2014, 53, 6073
259 Yun Yang,a,bJoanna Gurnham,cBoping Liu,bRobbert Duchateau,*aSandro Gambarotta*cIlia Korobkovd
Selective Ethylene Oligomerization with Chromium Complexes Bearing Pyridine-Phosphine Ligands: Influence of Ligand Structure on Catalytic Behavior.
Organometallics 2014, 33, 5749
260. Ahmed Alzamly, Sandro Gambarotta and Ilia Korobkov
Reactivity with Alkyl Aluminum of a Chromium Complex of a Pyridine-Containing PNP Ligand: A Redox N-P Bond Cleavage.
Organometallics 2014, 33, 1602
261. Shaneesh Vadake Kulangara, Daniel Haveman, Bala Vidjayacoumar, Ilia Korobkov, Sandro Gambarotta, and Rob Duchateau
Effect of Cocatalysts and Solvent on Selective Ethylene Oligomerization
Organometallics 2015, 34, 1203
262. Camilo J. Viasus, Nicholas P. Alderman, Sebastiano Licciulli, Ilia Korobkov and Sandro Gambarotta. Radical behavior of CO2 versus its deoxygenation promoted by vanadium aryloxide complexes: how the geometry of intermediate CO2-adducts determines the reactivity.
Chem. Eur.J. 2017, 23,17269–17278.
263. Jacob M. Sommers1, Nicholas P. Alderman1, Camilo J. Viasus1,2, Sandro Gambarotta1*
Revisiting the behavior of BiVO4as a carbon dioxide reduction photo-catalyst.
Dalton Transaction 2017, 6404
264. Nicholas P. Alderman1, Jacob M. Sommers1, Camilo J. Viasus1,2, Christine H.T. Wang1, Virginie Peneau1, SandroGambarotta1*, Balamurugan Vidjayacoumar3, Khalid A. Bahily-Al3: Photochemical Water Splitting Mediated by a C1 Shuttle
Dalton 2017,46, 49.
265. Camilo J. Viasus, Nicholas P. Alderman, Bulat Gabidullin and Sandro Gambarotta. Reaction of CO2with a Vanadium(II) Aryloxide: Synergistic Activation of CO2/-oxo Groups towards H-Atom Radical Extraction.
Angew. Chem. Int. Ed.2018, 57, 10928-10932.
266. Nicholas P. Alderman, Virginie Peneau,Camilo J. Viasus, Ilia Korobkov, Balamurugan Vidjayacoumar, Khalid Albahily and Sandro Gambarotta, Syn-gas from Waste: the Reduction of CO2with H2S.
React. Chem. Eng., 2019, 4, 763-771.
267. Camilo J. Viasus, Nicholas P. Alderman, Virginie Peneau, Bulat Gabidullin, Balamurugan Vidjayacoumar, Khalid Albahily and Sandro Gambarotta. Two-Step Catalytic Dehydrogenation of Formic Acid to CO2via Formaldehyde.
International Journal of Hydrogen Energy. 2019,44, 3, 1534-1543
268. Nicholas P Alderman, Virginie Peneau, Camilo J. Viasus, Ilia Korobkov, Balamurugan Vidjacoumar, Khalid Bahily-Al and Sandro Gambarotta. Efficient Reduction of Formic Acid to Formaldehyde by Zinc.
Canadian Journal of Chemistry., 2019, 97(1), 42-45.
269. Camilo J. Viasus, Sandro Gambarotta, Bulat Gabidullin. "Linear and Bridging End-On coordination modes of CO2 on vanadium(II) and (III) aryloxides"
Angewandte Chemie Int Ed Engl. VIP accepted
Patents
- · ‘Hydrogen production from aqueous formaldehyde under mild basic conditions’, 2017, US Patent Application 16T&I0165
- · ‘Hydrogen production from water using iron sulphide catalyst’, 2017, US Patent Application 17T&10012
- · ‘Formaldehyde from formic acid with production of metal oxide’, 2017, US Patent Application 62/468,483
- · ‘Production of acetic acid and hydrogen in an aqueous medium from ethanol and acetaldehyde via an organic/inorganic catalyst’, 2016, US Patent Application 62/343,396
- · ‘Carbon mediated water-splitting using formaldehyde’, 2016, US Patent Application 15/150,680
- 15T&I0029-US-PSP Light-Switchable Catalyst for the Hydrogen Production from para-Formaldehyde. Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
- 15T&I0029 Light-Switchable Catalyst for the Hydrogen Production from p-Formaldehyde. Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
- 15T&I0040-US-PSP Robust Catalyst for Hydrogen Production from p-Formaldehyde Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
- 15T&I0040 Robust Catalyst for the Hydrogen Production from p-Formaldehyde Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
- 15T&I0076 Catalytic Hydrogen Production from p-Formaldehyde Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
- 15T&I0089 Carbon Mediated Water Splitting using Formaldehyde Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick; Peneau, Virginie
- 15T&I0089 Carbon Mediated Water-Splitting Using FormaldehyCatalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick; Peneau, Virginie
- 15T&I0029-GC-NP Light-Switchable Catalyst for the Hydrogen Production from para-Formaldehyde. Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
- 16T&I0018-US-PSP Production of Acetic Acid and Hydrogen in an Aqueous Medium from Ethanol and Acetaldehyde via an Organic/Inorganic Catalyst Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick; Peneau, Virginie
- 16T&I0018 Production of Acetic Acid from Ethanol in Aqueous Medium Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick; Peneau, Virginie
- 15T&I0040-WO-PCT Robust Catalyst for Hydrogen Production from p-Formaldehyde Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
- 15T&I0040-GC-NP Robust Catalyst for Hydrogen Production from p-Formaldehyde Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
- 15T&I0029-CN-PCT Light-Switchable Catalyst for the Hydrogen Production from para-Formaldehyde. Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
- 16T&I0148 Hydrogen Production from Ethylene Glycol under Basic Conditions Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Thapa, Indira
- 16T&I0149 Formaldehyde from formic acid reduction with water using zinc Oxide Production Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick; Peneau, Virginie
- 16T&I0165 Hydrogen Production using Formaldehyde with Water under Mild Basic Conditions Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick; Peneau, Virginie
- 15T&I0029-US-NP Light-Switchable Catalyst for the Hydrogen Production from para-Formaldehyde. Catalysis-CRD and Uottawa Vidjayacoumar, Balamurugan; Al-Bahily, Khalid Gambarotta, Sandro; Alderman, Nick
Chapters in Encyclopedia
1. P.Berno, D. Richeson, S.Gambarotta
Vanadium
Comprehensive Organometallic Chemistry. Update 1982-1992 G. Wilkinson Ed, Pergamon Press, Oxford.
2. J. Jubb, D.Richeson, J. Song, S. Gambarotta
Comprehensive Organometallic Chemistry. Update 1982-1992 Zirconium and Hafnium G. Wilkinson Ed, Pergamon Press, Oxford.
Invited Lectures at Symposia, International Conferences an
1. S. Gambarotta "Reaction of Schiff base transition metal complexes with small molecules". - University of Groningen, Chemistry Dept., Groningen June 1986.
2. S. Gambarotta "Tetradentate Schiff base complexes of transition metals. A chemical curriculum of a ligand".
- Columbia University, Chemistry Dept., Nov. 1985
- Boston University, Chemistry Dept., Boston, March 1986.
- Dalhousie University, Chemistry Dept., Halifax April 1986
- Université Laval, Chemistry Dept., Quebec May 1986
3. S. Gambarotta
"Low-valent zirconium and hafnium: synthesis, reactivity and structure".
- University of Maryland, College Park, April 1988
- West Virginia University, Morgantown, April 1988 - Princeton University, Princeton, April 1988
- University of Ottawa, Ottawa, April 1988
- Columbia University, New York, April 1988
4. S. Gambarotta
"Low-valent zirconium: synthesis reactivity and structure" Chemistry Dept., University of Oldenburg, Oldenburg FRG, Oct.
11, 1988
5. S. Gambarotta
"Coordination chemistry in brief".
DSM Mastricht The Netherlands Nov. 1988
6. S. Gambarotta
"Is a Cr-Cr multiple bond an artefact?"
- Chemistry Dept., University of Ottawa, Canada Dec. 1988
- Shell Laboratories, Amsterdam (KSLA) January 1989
- Chemistry Dept., University of Nijmeghen, The Netherlands
Feb. 1989
- Chemistry Dept., University of Amsterdam, The Netherlands
March 1989
7. S. Gambarotta
Short metal-metal contacts: bonds, magnetic interactions and ligand artifacts in the chemistry of low-valent early transition metals.
University of Strasbourgh may 18, 1990
8. S.Gambarotta
Short M-M contacts between low-valent early transition metals: a vanishing borderline between M-M bonds and ligand artifacts".
- Chemistry Department, University of California Berkeley,
March 1991
- Chemistry Department, University of Guelph Feb 1991
- Chemistry Department, University of Windsor March 1991
- Chemistry Department, Carleton University, Summer 1991
10. S.Gambarotta
Supershort superweak Cr-Cr bonds
- Harvard/MIT Inorganic Seminar Program, Cambridge, Sept. 16, 1992
- Dartmouth College, Inorganic Seminar Program, Hanover, Apr. 28, 1993
11. S. Gambarotta
Recent results in the chemistry of low-valent vanadium and
titanium.
- Purdue University, West-Lafayette, October 19, 1993
- Universite' de Montreal July 10 1994
12. S.Gambarotta
Role of the ligand in enforcing short and supershort M-M bonds.
- University of Iowa, Iowa City, October 15, 1993
- Indiana University, Bloomington, October 18, 1993
13. S. Gambarotta
Recent advances in low-valent early transition metal chemistry
Pacifichem, Honolulu 1995
14. S. Gambarotta. Vanadium catalyzed olefin copolymerization. ESTAC Tech Day, Toronto, Nov. 9 1998
15. S. Gambarotta. New vanadium-based Ziegler-Natta catalysts. Breaking a paradigm.
High Polymer Forum, Quebec City, Aug. 1998
16. S. Gambarotta, Low-valent early transition metal amides: a chemical cornucopia
Technische Universitat Munich (Germany) Dec. 1997
Anorganische Chemie, Universitat Goettingen (Germany), Dec 1997
Anorganische Chemie, Universitat Hamburg (Germany), Dec 1997
Anorganische Chemie, Universitat Wurzburg (Germany), Dec 1997
Facolta Ingegneria, Universita Lecce (Italy) Dec 1997
University of Utah, Salt Lake City (April 1998)
State University Utah, Logan (April 1998)
University of Wyoming, Laramie (April 1998)
Colorado State University, Fort Collins (April 1998)
17. S. Gambarotta,Early Transition metal Amide, CIC Annual Meeting Windsor, June 1997
18. S. Gambarotta, Progress recent dans la chimie des premieres metaux de transition dans les bas etats d’oxidation.
- Universite de Sherbrooke, Feb. 1997
- Universite du Quebec a Montreal Feb. 1997
19. S. Gambarotta,Dinitrogen Fixation Activation promoted by low-valent ETM amides University of Victoria Feb 1996.
20. S. Gambarotta, Low-valent lanthanides and actinides as reagent for molecular activation processes
Simon Fraser University, Dec 1999.
21. S. Gambarotta, Dinitrogen activation promoted by low-valent lanthanides. May 2000 CSC annual meeting. Calgary
22. S. Gambarotta, C-X bond activation. May 2000, CSC annual meeting, Calgary.
23. S. Gambarotta, Vanadium Ziegler-Natta: problem, promises and challenges
High Polymer Forum, Aylmer Aug. 2000.
24. S. Gambarotta. Recent advances in dinitrogen activation. Pacifichem Dec. 2000.
25. S. Gambarotta. Multi electron redox processes promoted by lanthanide clusters. Pacifichem Dec. 2000.
26. S. Gambarotta. Cooperative reduction of dinitrogen promoted by lanthanide clusters. Annual Symposium on Lanthanide Chemistry. Stuttgart. Dec. 2000.
27. S. Gambarotta. Cooperative reduction of dinitrogen promoted by lanthanide clusters. University of Koeln. Dec. 2000.
28. S. Gambarotta. Vanadium Complexes as Ziegler-Natta Catalysts. University of Berlin Dec. 2000.
29. S. Gambarotta. Recent advances in actinide and lanthanide chemistry. Gordon Conference, Newport, July 2001.
30. S. Gambarotta. Vanadium Complexes as Ziegler-Natta Catalysts. Promises and Challenges. Third International Symposium on Vanadium Chemistry Osaka Nov 2001.
31. S. Gambarotta. Highly reactive block f metal complexes. Waseda University Tokyo. Nov 2001
32. S. Gambarotta. Who said that uranium chemistry is boring. Exciting results from the chemistry of giant atoms. University of Rochester Nov. 2001.
33. S. Gambarotta. Actinide chemistry. Activation of small molecules by using giant atoms
Purdue University Oct 2003
Indiana University Oct 2003
34. G. Scholss lecturer University of Chicago Dec 2002
35. Am2Net Munster 2004;
36. ASm2Net Calgary 2005
37. Pacifichem 2005 (2 lectures);
38. Rare Earth Conference Bayereuth 2004.
39. Basell Frankfurt 2006;
40 ACS (San Francisco) Sept 2006
41 CIC meeting (Halifax)
42. Catalysis Symposium University of Florida April 2006;
43. Dutch Polymer Institute meeting
44. Am2Net Muenster 2007
45. OZOM Camberra January 2008;
Contributed Papers at Conferences and Meetings
1. S. Gambarotta and C. Floriani
"The role of bifunctional complexes in the activation of CO2 and CO2 analogues".
EUCHEM Conference, Venice, Sept. 28-30, 1982.
2. S. Gambarotta and S. Strologo
"Decamethylvanadocene: a novel model compound in coordinative addition reactions".
Italian Chemical Society Inorganic Meeting, Bari Sept. 27,
1982.
3. S. Gambarotta
"Diazoalkanes in organometallic chemistry: coordination and
metal-promoted transformations".
XXII ICCC, Budapest, Aug. 23-27, 1982.
4. S. Gambarotta, M.L. Fiallo
"Disulphur complexes and desulphurization reactions of the C+S functionality".
Italian Chemical Society Meeting Ferrara, Sept. 12-16, 1983. 5.
S. Gambarotta
"Carbon-carbon bond forming and breaking by a metal-assisted redox process in a nickel(II)-Schiff base complex".
Italian Chemical Society Inorganic Meeting, Ferrara, Sept. 12-16, 1983.
6. S. Gambarotta
"Bifunctional complexes promoting C-C bond formation from carbon dioxide related molecules".
7. S. Gambarotta, Y. Wielstra, M. Chiang
"Monocyclopentadienyl zirconium (II) chemistry" ACS 20th central regional meeting
Morgantown, West Virginia USA, June 1988
8. S. Gambarotta, M. Chiang
"Metal-metal bond formation in the chemistry op Zr(III)".
Third Chemical Congress of North America
Toronto, Canada, June 5 1988
9. J. Edema, S. Gambarotta
"Molecular complexity in the chemistry of Cr(II) alkoxides. The role of the alkali cation."
199th ACS National Meeting, Boston april 22-27, 1990
10. J. Edema, S. Gambarotta
"V(II) amine complexes: an easy entry in the chemistry of
divalent vanadium."
199th ACS National Meeting, Boston april 22-27, 1990
11. Y. Wielstra, S. Gambarotta
Binuclear fulvalene Zr(III) and Zr(IV) complexes: synthesis, structure and reactivity."
199th ACS National Meeting, Boston april 22-27, 1990
12. J. Edema, S. Gambarotta
"Short Cr-Cr distance in dimeric Cr(II) complexes: quadruple bonds or ligand artifacts?"
199th ACS National Meeting, Boston april 22-27, 1990
13. S.Gambarotta, J.Edema
Short M-M distances in dimeric Cr(II) and V(II) complexes: M-M multiple bonds or ligand artifacts?
-C.I.C. Congress, July 15-20, Halifax, 1990.
14. S.Gambarotta, R. Duchateau
Recent Development in the chemistry of low-valent titanium
-C.I.C. Congress, Hamilton, 1991.
15. S.Gambarotta, R. Duchateau
Coordination chemistry of divalent titanium: dinitrogen
fixation and disproportionation reactions.
203rd American Chemical Society Meeting, San Francisco, April 1992
16. S.Gambarotta, S. Hao
Reversible cleavage of Cr-Cr quadruple bond
203rd American Chemical Society Meeting, San Francisco, April 1992
17. S.Gambarotta, P. Berno
The role of the ligand steric hindrance in determining the stability of very short V-V bonds.
Okazaki Conference on Early Transition Metals, Okazaki (Japan) Aug. 1 1994
18. S. Gambarotta
New catyalysis using an old ligand
CIC conference London (Ont) 1994
List of Collaborators
I was the only supervisor of: Y. Wielstra, Ph.D.(1990,) Philips Laboratories Eindhoven (The Netherlands); J. Edema, Ph.D. (1991), General Electrics (USA/The Netherlands); R. Duchateau, Rijksuniversiteit Groningen (The Netherlands); L. Scoles, M.Sc. (1994), Res. Associate NRC labs; S. Hao, Ph.D. (1994), P.D.F. University of Windsor; R. Minhas, Ph.D.,(1995); ); Y. Ma M.Sc. (1998); N. Desmangles M.Sc (1997).; T. Dubbe, Ph.D..; Myriam Tayebani, Ph.D.; Feghali Khalil, M.Sc. (Photochemical, Montreal, 1998), Damien Reardon M.Sc.; J. Jubb, P.D.F. (1994) Shell Laboratories (Amsterdam);P. Berno, Environment LTD (Italy); D. Dick, P.D.F. (1992), Wayne State University (USA); N. Beydhoun, P.D.F. (1992), Universite de Strasbourg (France); J. Song, P.D.F. Samsung Research, Seoul South Korea; H. Jenkins, P.D.F. (co-supervised with Dr. Richeson); M. Histead, P.D.F. (1990), Technical Staff U. of Ottawa; M. Moore, P.D.F.; K. Ruppa, P.D.F.(U. of Alberta); A. Kasani P.D.F., Istvan Covacs P.D.F. (McGill); Francoise Conan, P.D.F. (Universite' de Brest); P.D.F.; Shirley Wong (Res. Ass.) Kanox (Ottawa). Aharonian Ghazar (PDF), Sabrina Conoci (PDF), Ilia Korobokov (PDF), Mani Ganesan (PDF), Jingwen Guan(PDF), Carola Schultzke (PDF), Christian Berube (MSc), David Enright (MSc), David Harding(PDF), Hiroyasu Sajiyama (PDF), Sajjad Mohebi(PDF), Emeric Lefebvre (visiting PhD), Jennifer Scott (PhD), Patrick Crewdson (PhD), Jalil Assoud (PDF), Dominique Freckmann, Christopher McManus, Huang Gao (PDF), Davide Alberti (PDF), Sugandi Idalgo (PDF), Grigory Nikirov (PDF) Bala Vidyacoumar (PDF), Claire Temple (PDF) Terri Clarke (MSc), Indu Vidyaratne (MSc), Ilia Korobkov (PhD), Harminder Phull (MSc), Amir Jabri (PhD), Khalid Albahili (PhD), Vladimir Shuster (MSc), Steven Horvath (MSc), Indira Thapa (PhD), Elena Smolenski (PDF), Chris Mason (MSc).
Honorary Memberships and Awards
1. Member of the Editorial Board of J. of Organometallic Chemistry (1994-1998);
2. Alcan Lecture Award 1996;
3. Fellow of the Chemical Institute of Canada;
4. NSERC GSC (Committee 24, 2001-2004).
5. 2002 Gerhard Schloss Lecturer, University of Chicago.
6. 2002-2005 Member of the Editorial Board of Organometallics