Recent Publications & Patents (2005-2011)
2011
11-6. "Reactions of Grubbs Catalysts with Excess Methoxide: Novel Methoxyhydride Complexes of Ruthenium." N.J. Beach, J.A.M. Lummiss, J.M. Bates, D.E. Fogg*, Organometallics, submitted (Manuscript ID: om-2011-01288p).
11.5. "Ethylene-promoted vs. ethylene-free enyne metathesis." A.G.D. Grotevendt, J.A.M. Lummiss, M.L. Mastronardi, D.E. Fogg*, J. Am. Chem. Soc. 2011, 133, 15918-15921.
11-4. "A reactive Ru-binaphtholate building block with self-tuning hapticity." J.M. Blacquiere, C.S. Higman, R. McDonald, D.E. Fogg*, J. Am. Chem. Soc. 2011, 133, 14054-14062.
11-3. "Expanding the "ROMP Toolbox" for tissue engineering: Assessing the design criteria for Ru-pseudohalide initiators." S. Monfette, J.C. Conrad, K.D. Camm, D.E. Fogg*, Poly. Prepr., 2011, 52-53.
11-2. "Unprecedentedly Strong Binding of Dinitrogen at Ruthenium." J.M. Blacquiere, C.S. Higman, S.I. Gorelsky, N.J. Beach, S.J. Dalgarno, D.E. Fogg*, Angew. Chem. Int. Ed. 2011, 50, 916-919.
11-1. "The Future, Faster: Using High-Throughput Experimentation to Accelerate Discovery in Organometallic Chemistry." S. Monfette, J. M. Blacquiere, D.E. Fogg*, Organometallics 2011, 30, 36-42. (invited contribution for "The Future of Organometallic Chemistry").
2010
10-5. "Hydrogenolysis versus Methanolysis of First- and Second-Generation Grubbs Catalysts: Rates, Speciation, and Implications for Tandem Catalysis." N.J. Beach, K.D. Camm, D.E. Fogg,* Organometallics 2010, 29, 5450-5455 (invited: special issue in honour of Dietmar Seyferth).
10-4. "Ring-Closing Metathesis Synthesis of Medium and Large Rings: Challenges and Implications for Sustainable Synthesis", S. Monfette, D.E. Fogg*, in Green Metathesis Chemistry, NATO Adv. Chem. Series; V. Dragutan, E. Finkelshtein, Eds, 2010.
10-3. "Getting RCM Off the Bench: Reaction-reactor matching transforms metathesis efficiency in the continuous-flow assembly of large rings." S. Monfette, M. Eyholzer, D.M. Roberge*, D.E. Fogg*, Chem. Eur. J. 2010, 16, 11720-11725. (Collaboration with LONZA, Switzerland)
10-2. "Integrating the Schrock and Grubbs Catalysts: Ru-binaphtholate catalysts for olefin metathesis." J.M. Blacquiere, R. McDonald, D.E. Fogg*, Angew. Chem. Int. Ed. 2010, 49, 3807-3810.
10-1. "Monitoring Ring-Closing Metathesis: Limitations on the Utility of Routine 1H NMR Spectroscopy", S. Monfette, A.K. Crane, J.A. Duarte Silva, G.A. Facey, E.N. dos Santos, M. Araujo, D.E. Fogg,* Inorg. Chem. Acta (special issue in honour of Paul Pregosin)
2009
09-6. "Geometric and Electronic Structure of a C1-Symmetric Ru-Aryloxide Metathesis Catalyst: An Experimental and Computational Study", M.W. Kotyk, S.I. Gorelsky, J.C. Conrad, C. Carra, D.E. Fogg*, Organometallics 2009, 28, 5424-5431.
09-5. "Synthetic Neoglycopolymer-Recombinant Human Collagen Hybrids As Biomimetic Crosslinking Agents in Corneal Tissue Engineering", K. Merrett, W. Liu, D. Mitra, K.D. Camm, C.R. McLaughlin, Y. Liu, M.A. Watsky, F. Li, M. Griffith, D.E. Fogg*, Biomaterials, 2009 30 5403-5408.
09-4. "Equilibrium Ring-Closing Metathesis", S. Monfette, D.E. Fogg*, Chem. Rev. (invited review: Thematic Issue on Carbenes in Chemistry), 2009, 109, 3783-3816.
09-3. "Electronic Effects of the Anionic Ligands in Ru-Catalyzed Olefin Metathesis", S. Monfette, K.D. Camm, S. Gorelsky, D.E. Fogg*, Organometallics, 2009, 28, 944-946.
09-2. "Carbonyl-Amplified Catalyst Performance: Balancing Stability against Activity for Five-Coordinate Ruthenium Hydride and Hydridocarbonyl Catalysts", N.J. Beach, J.M. Blacquiere, S.D. Drouin, D.E. Fogg*, Organometallics, 2009, 28, 441-447.
09-1. "Dissecting Out the Effect of Ru-OAr Bonding in a Five-Coordinate Complex of Ruthenium (II)", S. Monfette, J.A. Duarte Silva, S.I. Gorelsky, S.J. Dalgarno, E.N. dos Santos, M.H. Araujo, D. E. Fogg*, Can. J. Chem. 2009, 87, 361-367 (special issue in honour of Dick Puddephatt).
2008
08-5. "Time as a Dimension in High-Throughput Homogeneous Catalysis", J.M. Blacquiere, T. Jurca, J. Weiss, D.E. Fogg*, Adv. Syn. Catal. 2008, 350, 2849-55.
08-4. "Inside the Black Box: Perspectives on Transformations in Catalysis" (Strem Award Lecture; invited cover article), D.E. Fogg*, Can. J. Chem., 2008, 86, 931-941.
08-3. "The Mechanism of Olefin Hydrogenation Catalyzed by RuHCl(L)(PR3)2 Complexes (L=CO, PR3)", C.N. Rowley, H.M. Foucault, T.K. Woo*, D.E. Fogg*, Organometallics, 2008, 27, 1661-1663.
08-2. "Convenient Routes to Versatile Ruthenium Hydridocarbonyl Catalysts Containing Electron-Rich Ancillary Ligands", N.J. Beach, U.L. Dharmasena, S.D. Drouin, D.E. Fogg*, Adv. Synth. Catal. 2008, 350, 773-777.
08-1. "MALDI Mass Spectrometry as a Tool for Insight in Organotransition-Metal Catalysis." M.D. Eelman, J.M. Blacquiere, M.M. Moriarty, D.E. Fogg*, Angew. Chem. Int. Ed., 2008, 47, 303-306 (VIP Paper; featured on inside cover).
2007
07-5. "Tandem ROMP-Hydrogenation with a Third-Generation Grubbs Catalyst." K.D. Camm, N. Martinez Castro, Y. Liu, P. Czechura, D.E. Fogg*, J. Am. Chem. Soc., 2007, 129, 4168-4169.
07-4. "Oligomers as Intermediates in Ring-Closing Metathesis." Jay C. Conrad, Melanie D. Eelman, Jo‹o A. Duarte Silva, Sebastien Monfette, Henrietta H. Parnas, Jennifer L. Snelgrove, and Deryn E. Fogg*, J. Am. Chem. Soc., 2007, 129, 1024-1025.
07-3. "Transition Metal Catalysts in Organic Synthesis: Ring-Opening Metathesis Polymerization." D.E. Fogg*, H. Foucault, Comprehensive Organometallic Chemistry III, R.H. Crabtree, D.M.P. Mingos, Eds., Elsevier: Oxford 2007, Vol. 11, Ch. 6.3, pp. 623-652.
07-2. "From Drug Cocktails to Tissue Engineering: Synthesis of ROMP Polymers for Biological Applications." K.D. Camm, D.E. Fogg*, in Metathesis Chemistry: Nanostructure Design to Advanced Materials, NATO Adv. Chem. Series; Y. Imamoglu, V. Dragutan, Eds., 2007, p. 285-303.
07-1. "Ru-Aryloxide Catalysts for Olefin Metathesis." S. Monfette, J.C. Conrad, J.M. Blacquiere, N. Beach, D.E. Fogg*, in Metathesis Chemistry: Nanostructure Design to Advanced Materials, NATO Adv. Chem. Ser.; Y. Imamoglu, V. Dragutan, Eds., 2007, p. 79-89.
2006
06-P2. "Saturated Neoglycopolymers as Collagen Cross-linking Agents." D.E. Fogg, Y. Liu, M. Griffith, US Patent App., US 11/442,755, filing date May 30, 2006.
06-P1. "Tandem ROMP-Hydrogenation Catalysis." D.E. Fogg, K.D. Camm, U.S. Provisional Patent, 2006, US 60/824,345.
06-8. "A Chelate-Stabilized Ruthenium(σ-Pyrrolato) Complex." H.M. Foucault, D.L. Bryce*, D.E. Fogg*, Inorg. Chem. 2006, 45, 10293-10299.
06-7. "Mass Spectrometric Analysis of Organometallics: Ionization Mechanisms and the Probability of Survival." M.D. Eelman, M.M. Moriarty, D.E. Fogg*, Educ. Adv. Chem. (invited), 2006, 10, 213-234.
06-6. "Ruthenium Metathesis Catalysts containing Chelating Aryloxide Ligands." S. Monfette, D.E. Fogg*, Organometallics, 2006, 25, 1940-1944.
06-5. "Ru-Aryloxide Metathesis Catalysts with Enhanced Lability." J.C. Conrad, K.D. Camm, D.E. Fogg*, Inorg. Chim. Acta (invited; van Koten issue), 2006, 359, 1967-1973.
06-4. "Ruthenium-Catalyzed Ring-Closing Metathesis: Advances, Limitations, and Opportunities." J.C. Conrad, D.E. Fogg*, Curr. Org. Chem. (invited), 2006, 10, 185-202.
06-3. "Exploring the Electronic Structure of Ru Catalysts using X-ray Absorption." M.U. Delgado-Jaime, J.C. Conrad, D.E. Fogg, P. Kennepohl*, Inorg. Chim. Acta, invited (B.R. James issue), 2006, 359, 3042-3047.
06-2. "Gold(I) NHC Complexes Bearing Biologically Compatible Moieties." P. de Frémont, E.D. Stevens, M.D. Eelman, D.E. Fogg, S.P. Nolan*, Organometallics, 2006, 25, 5824-5828.
06-1. "Ru-Aryloxide Catalysts in Metathesis." J.C. Conrad, J.L. Snelgrove, M.D. Eeelman, S. Hall, D.E. Fogg*, J. Mol. Catal. A (olefin metathesis issue: invited), 2006, 254, 105-110.
2005
05-5. "Highly Efficient Ru-Pseudohalide Catalysts for Olefin Metathesis." J.C. Conrad, H.H. Parnas, J.L. Snelgrove, D.E. Fogg*, J. Am. Chem. Soc. 2005, 127,11882-11883.
05-4. "Simultaneous Observation of Doubly- and Triply-Chloride Bridged IsomersÉ.Ó S.D. Drouin, S. Monfette, D. Amoroso, G.P.A. Yap, D.E. Fogg,* Organometallics, 2005, 24, 4721-4728.
05-3. "New Pseudohalide Ligands in Ru-Catalyzed Olefin Metathesis: A Robust, Air-Activated Iminopyrrolato Catalyst." S.D. Drouin, H. M. Foucault, G.P.A. Yap, D. E. Fogg*, Can. J. Chem. (special issue in honour of Howard Alper), 2005, 83, 748.
05-2. "N-Heterocyclic Carbenes as Activating Ligands in Hydrogenation and Isomerization of Unactivated Olefins." U. Dharmasena, H. M. Foucault, E.N. dos Santos, D.E. Fogg*, S. P. Nolan, Organometallics, 2005, 24,1056.
05-1. "Inhibiting s-p Isomerization of Aryloxide in Late Transition Metal Complexes." J.L. Snelgrove, J. Conrad, M. Eelman, M.M. Moriarty, G.P.A. Yap, D. E. Fogg*, Organometallics, 2005, 24, 103-109.
